Ambident Reactivity in the Phenyl + NO Radical Recombination
ABSTRACT The recombination reaction of nitric oxide (NO) with radicals via its oxygen atom, rather than the more common nitrogen site, offers an intriguing pathway to the formation of oxynitrenes. The photochemical isomerization of nitroso compounds into their corresponding oxynitrenes may involve such a step.
Virinder Bhagat +3 more
wiley +1 more source
Reactions of vicinal aliphatic bis(hydroxylamines) with trifunctionalized methane derivatives
Evgeny A. Mostovich +2 more
doaj +1 more source
Engineering Enantiocomplementary Protoglobins for Stereoconvergent Construction of <i>N</i>-Alkylated α-Aminoketones. [PDF]
Qin ZY +8 more
europepmc +1 more source
Synthetic Strategies for Activity‐Based Probes to Decode Ubiquitin‐Like Modifiers
ABSTRACT Ubiquitin‐like proteins (Ubls) such as SUMO, NEDD8, ISG15, URM1, UFM1, FAT10, ATG8/ATG12, and FUBI are essential regulators of cellular homeostasis, controlling processes from protein stability and trafficking to immune signaling and autophagy.
Saibal Chanda +5 more
wiley +1 more source
Nitrones: Comprehensive Review on Synthesis and Applications. [PDF]
Santos RALS, Silva AMS, Pinto DCGA.
europepmc +1 more source
Stabilized Bi(III) Sites Direct *NH2OH Pathway for Efficient Cyclohexanone Oxime Electrosynthesis
The electron‐buffering effect stabilizes Bi3+ sites under electroreductive conditions, preserving a favorable interfacial water configuration that sustains the selective *NH2OH pathway and enables efficient cyclohexanone oxime electrosynthesis. ABSTRACT Coupling electrocatalytic nitrite reduction reaction (NO2−RR) with cyclohexanone conversion enables ...
Zichao Xi +8 more
wiley +1 more source
Cyclic Hydroxylamines for Native Residue-Forming Peptide Ligations: Synthesis of Ubiquitin and Tirzepatide. [PDF]
Han J +5 more
europepmc +1 more source
Sum Frequency Generation spectroscopy is an advanced nonlinear optical vibrational technique for probing molecules at boundaries, such as gas–liquid, liquid–solid, and gas–solid interfaces, providing information on reaction kinetics and mechanism that allowoptimization to design the ideal catalytic surface.
Zohreh Moghaddasi +3 more
wiley +1 more source
A cyanide‐free cascade integrating photocatalysis and biocatalysis is presented. Benzyl alcohols undergo light‐driven oxidation–oximation to form oxime intermediates, which are subsequently converted into benzonitriles through dehydration catalyzed by an engineered aldoxime dehydratase.
Luca Nespoli +3 more
wiley +1 more source
Endocyclic Trisubstituted Hydroxylamine Isosteres of Basic Amines for ADME Modulation and Reduction of hERG Activity. [PDF]
Khan I +3 more
europepmc +1 more source

