Results 21 to 30 of about 10,973 (280)

Mild and selective catalytic oxidation of organic substrates by a carbon nanotube-rhodium nanohybrid [PDF]

open access: yes, 2015
International audienceA heterogeneous catalyst was assembled by stabilization of rhodium nanoparticles on carbon nanotubes. The nanohybrid was used for the catalytic aerobic oxidation of diverse substrates such as hydroquinones, hydroxylamines, silanes ...
Donck, Simon   +8 more
core   +2 more sources

Synthesis of Alkyl Aryl Sulfones via Reaction of N-Arylsulfonyl Hydroxyamines with Electron-Deficient Alkenes

open access: yesMolecules, 2016
Alkyl aryl sulfones were prepared in high yields via the reaction of N-arylsulfonyl hydroxylamines with electron-deficient alkenes. These reactions have the advantages of simplicity, easily available starting materials and mild reaction conditions.
Yunhui Bin, Ruimao Hua
doaj   +1 more source

Selective conversion of nitroarenes using a carbon nanotube-ruthenium nanohybrid [PDF]

open access: yes, 2015
International audienceRuthenium nanoparticles were assembled on carbon nanotubes and the resulting nanohybrid was used in the hydrazine-mediated catalytic hydrogenation of various nitroarenes, at room temperature.
Boudet, Caroline   +7 more
core   +4 more sources

A direct approach to amines with remote stereocentres by enantioselective CuH-catalysed reductive relay hydroamination [PDF]

open access: yes, 2015
Amines with remote stereocentres (stereocentres that are three or more bonds away from the C–N bond) are important structural elements in many pharmaceutical agents and natural products.
Buchwald, Stephen Leffler   +2 more
core   +1 more source

Polyalkoxy Nitrones as Chiral Building Blocks in Asymmetric Synthesis

open access: yesMolecules, 1999
Optically active nitrones derived from both aldoses and dialdoses add metallated heterocycles in a stereocontrolled way depending on the nature of the Lewis acid used as a precomplexing agent of the nitrone.
Tomás Tejero, Pedro Merino
doaj   +1 more source

Electrochemical Evaluation of Nitroxyl Radical Catalysts and Electrochemical Detection of Cyclosporin A

open access: yesInternational Journal of Electrochemical Science, 2021
Nitroxyl radical catalysts oxidize alcohols under an applied electric potential. It is possible to quantify the alcohol concentration from the resulting oxidation current.
Sachiko Komatsu   +10 more
doaj   +1 more source

Asymmetric additions to dienes catalysed by a dithiophosphoric acid. [PDF]

open access: yes, 2011
Chiral Brønsted acids (proton donors) have been shown to facilitate a broad range of asymmetric chemical transformations under catalytic conditions without requiring additional toxic or expensive metals.
Hamilton, Gregory   +4 more
core   +2 more sources

Oxidation of N,N-Disubstituted Hydroxylamines to Nitrones: The Search for More Sustainable Selective and Practical Stoichiometric Oxidants

open access: yesCHIMIA, 2017
Nitrones are key intermediates for the total synthesis of nitrogen-containing natural products and analogues. The direct oxidation of the corresponding N,N-disubstituted hydroxylamines is one of the most straightforward methods to access such ...
Camilla Matassini, Francesca Cardona
doaj   +1 more source

Precursor‐Directed Synthesis of Apoptosis‐Initiating N‐Hydroxyalkyl Phenylbenzoisoquinolindione Alkaloids

open access: yesChemistryOpen, 2022
A precursor‐directed approach to access N‐hydroxyalkyl phenylbenzoisoquinolindiones (PBIQs) has been developed. Incubation of plant material of Xiphidium caeruleum with hydroxylamines of various chain lengths (C2, C4, C6, C8, C10 and C12) resulted in 11 ...
Prof. Dr. Yu Chen   +3 more
doaj   +1 more source

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