Results 91 to 100 of about 95,661 (297)
Angewandte Chemie, EarlyView.A Keplerate, an inorganic, porous buckyball was used as a host for copper metal cations ligated by histidine surrogates. Prepared by a simple assembly technique, the guest–host complex was used as a primitive biomimetic model of a monooxygenase enzyme complex, where C─H bonds were electrocatalytically hydroxylated by oxygen under reducing conditions ...
Eynat Haviv +4 more
wiley +2 more sources
Advanced Science, EarlyView.This Review shows how cerium oxide helps water‐splitting catalysts work better and last longer. It explains how CeO2 tunes electronic structure, oxygen‐vacancy behavior, and surface reconstruction, while adapting to alkaline, acidic, and seawater conditions.
Zhen Cui +9 more
wiley +1 more source
An IscS Persulfide Donates the Sulfur for Ribosomal Protein uL16 Thioamidation
Angewandte Chemie, EarlyView.YcaO‐catalyzed thioamidation of the ribosomal subunit protein uL16 is widespread in Pseudomonadota bacteria. We identify the iron–sulfur cluster cysteine desulfurase IscS as the sulfur donor via an IscS persulfide and observe direct IscS–uL16 interactions.
Yanqing Xue +2 more
wiley +2 more sources
Photochemical Regiodivergent Functionalization of Quinolines with Aryl Ketones
Advanced Science, EarlyView.A photocatalytic system‐controlled approach enables regiodivergent C2‐ and C4‐functionalization of quinolines with aryl ketones by optimizing aryl thiol photocatalysts and formate reductants. Using ortho‐(isopropoxycarbonyl)thiophenol with excess formate facilitates C4‐dearomatization, yielding bridged 1,3‐oxazepanes. In contrast, meta‐(methoxycarbonyl)
Yi‐Lin Zhao +6 more
wiley +1 more source
Two-Component FAD-Dependent Monooxygenases: Current Knowledge and Biotechnological Opportunities
Biology, 2018 Flavoprotein monooxygenases create valuable compounds that are of high interest for the chemical, pharmaceutical, and agrochemical industries, among others. Monooxygenases that use flavin as cofactor are either single- or two-component systems.
Thomas Heine +4 more
doaj +1 more source
Surface‐State‐Driven Selectivity of Electrocatalytic Glucose Oxidation: Metallic Au, Au─OH, and CuO
Advanced Science, EarlyView.In the electrochemical oxidation of glucose, whether the pyranose ring opens upon adsorption decides the reaction pathway: ring opening on metallic Au yields gluconic acid, gluconolactone formation on Au─OH leads to glucaric acid, and C─C cleavage on CuO gives formic acid. Surface state thus governs product selectivity.
Myeonghwan Oh +9 more
wiley +1 more source
Role of prolyl hydroxylation in the molecular interactions of collagens [PDF]
, 2019 Co- and post-translational hydroxylation of proline residues is critical for the stability of the triple helical collagen structure. In this review, we summarise the biology of collagen prolyl 4-hydroxylases and collagen prolyl 3-hydroxylases, the ...
Heino, Jyrki +3 more
core +1 more source
Advanced Electronic Materials, EarlyView.An oxygen‐controlled iridium‐oxide (IrOx) nano‐net structure is developed to enhance the sensitivity of metal‐electrolyte‐metal‐insulator‐silicon (MEMIS) biosensors. Integrated with a deep learning model, this platform achieves a high accuracy of 94.8% for detecting the breast cancer biomarker LOXL2.
Chiao‐Fan Chiu +9 more
wiley +1 more source
When is a target not a target?
eLife, 2019 Cells rely on prolyl hydroxylase enzymes to sense low levels of oxygen, but they might act on fewer targets than previously thought.
David C Bersten, Daniel J Peet
doaj +1 more source
Alkane Hydroxylation by Peroxy Acids: A Comparison with the Cytochrome P450 Hydroxylation
, 2008 Alkane hydroxylation by peroxy acids proceeds by a synchronous nonconcerted peroxy oxygen insertion into the C-H bond according to density functional theory.
Groenhof, A.R. +5 more
core +2 more sources