Results 91 to 100 of about 350,851 (339)

Synthesis of 1-azaspiro[4.4]nonan-1-oxyls via intramolecular 1,3-dipolar cycloaddition

open access: yesBeilstein Journal of Organic Chemistry, 2019
Sterically shielded nitroxides of the pyrrolidine series have shown the highest resistance to reduction. Here we report the synthesis of new pyrrolidine nitroxides from 5,5-dialkyl-1-pyrroline N-oxides via the introduction of a pent-4-enyl group to the ...
Yulia V. Khoroshunova   +5 more
doaj   +1 more source

Luddin type anthraquinone glycosides from Putoria calabrica [PDF]

open access: yes, 2002
Two new lucidin type anthraquinone glycosides, putorinoside A (1) and putorinoside B (2) were isolated from Putoria calabrica, in addition to two known anthraquinone glycosides, lucidin 3-O-β-glucopyranoside (3) and lucidin 3-O-primeveroside (4).
Chris M. Ireland   +4 more
core   +1 more source

2-[2-(Hydroxymethyl)phenyliminomethyl]phenol

open access: yesActa Crystallographica Section E Structure Reports Online, 2004
Molecules of the title compound, C14H13NO2, are nearly planar. The molecular structure is stabilized by a strong intramolecular O—H⋯N hydrogen bond between the imine and hydroxyl groups [O⋯N = 2.614 (2) A]. In the crystal structure, intermolecular O—H⋯O hydrogen bonds [O⋯O = 2.681 (3) and 2.641 (3) A] link inversion-related mol­ecules into chains ...
Ersanli, CC   +3 more
openaire   +2 more sources

All‐Round Talent: Unique Zinc Guanidine Catalyst Performs Efficiently in Synthesis and Chemical Recycling of (Bio)Polyesters

open access: yesAdvanced Science, EarlyView.
A new zinc hybrid guanidine catalyst [Zn{(R,R)TMGNMe2(1,2)ch}2](OTf)2 (C1) shows very high catalytic activity in the polymerization of cyclic esters and in the depolymerization of these polyesters. Using C1 in the ring‐opening polymerization of lactide and caprolactone under industrially relevant conditions, astonishing rate constants of the same order
Tabea Becker   +8 more
wiley   +1 more source

Fractionation of human immune γ-globulin [PDF]

open access: yes, 1950
Equine and bovine serum proteins have recently been fractionated by means of a physical method utilizing an electrophoretic adaptation of the principles of the Clusius column (l-4), first described and tested by Kirkwood (5) and Nielsen (6).
Brown, Raymond A.   +3 more
core  

ZIF‐67‐Confined Pd Single‐Atom Catalysts Implanted Into Polydopamine‐Modified Bamboo Microchannels for Robust Continuous‐Flow Hydrogenation

open access: yesAdvanced Science, EarlyView.
The report presents a facile room‐temperature method to stabilize Pd single‐atom catalysts within ZIF‐67 crystals during their formation. Despite an ultralow Pd loading (0.0014 wt%), the catalytic microreactor, featuring atomically dispersed Pd‐N4 sites in ZIF‐67, demonstrates superior robustness and maximized Pd utilization, significantly ...
Sisi Yao   +6 more
wiley   +1 more source

The influence of in vitro gastrointestinal digestion on the chemical composition and antioxidant and enzyme inhibitory capacities of carob liqueurs obtained with different elaboration techniques [PDF]

open access: yes, 2019
Carob liqueur is a traditional Mediterranean alcoholic beverage obtained via a wide range of production techniques contributing to the different organoleptic attributes of the final product.
Coelho, Natacha   +5 more
core   +1 more source

Hydroxymethylation of DNA

open access: yes, 2014
EXCLI Journal ; Vol.
Richa, Rajneesh, Sinha, Rajeshwar P.
openaire   +2 more sources

Ionic–Bionic Interfaces: Advancing Iontronic Strategies for Bioelectronic Sensing and Therapy

open access: yesAdvanced Science, EarlyView.
Ionic–bionic interfaces for bioelectronics leverage ions as multifunctional mediators that combine mechanical compliance, ionic and electronic functionalities, and therapeutic effects. These systems offer real‐time biosignal transduction, effective wound dressing, responsive drug delivery, and seamless interaction between soft tissues and electronic ...
Yun Goo Ro   +6 more
wiley   +1 more source

Solvent and thermal stability, and pH kinetics, of proline-specific dipeptidyl peptidase IV-like enzyme from bovine serum [PDF]

open access: yes, 2007
Proline-specific dipeptidyl peptidase-like (DPP IV; EC 3.4.14.5) activity in bovine serum has attracted little attention despite its ready availability and the paucity of useful proline-cleaving enzymes.
Abbott   +43 more
core   +1 more source

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