Results 181 to 190 of about 189,846 (385)

Electronic Effects of Al Doping on the Mechanism of Methanol Formation on an Al Doped Cu/ZnO Interface Model

open access: yesChemCatChem, EarlyView.
Computational techniques are used to understand the electronic doping character of Al added to the Cu/ZnO catalyst system during interfacial methanol formation. Notably, some formate species behave as intermediates, others as spectators while the methoxy intermediate is a mechanistic dead end.
David A. Jurado A.   +3 more
wiley   +1 more source

Mesoporous Silica‐Based Photocatalytic Materials for Solar Energy Storage and Utilization

open access: yesCarbon Energy, EarlyView.
ABSTRACT The efficient storage and application of sustainable solar energy has drawn significant attention from both academic and industrial points of view. However, most developed catalytic materials still suffer from insufficient mass diffusion and unsatisfactory durability due to the lack of interconnected and regulatable porosity.
Rui Sun   +5 more
wiley   +1 more source

Recent Advances in Detergent Chemistry and Handling Support Membrane Protein Analysis Including Lipid Interactions

open access: yesChemistry – A European Journal, EarlyView.
Detergent design parameters determine experimental successes in membrane protein research. Recent progresses in detergent chemistry are reviewed to promote the top‐down design of non‐ionic detergents for the purification and analysis of intact membrane proteins, including lipid interactions.
Katharina Alker   +2 more
wiley   +1 more source

Chemical Synthesis of NICOL, A Coligand Secreted Protein Mediating Mammalian Male Reproductive Tract Trans‐luminal Signaling

open access: yesChemistry – A European Journal, EarlyView.
NICOL is a small protein engaged the sperm maturation in the epididymis. The recombinant expression of NICOL is low‐yielding and highly heterogeneous, which retards the precise understanding of the function of NICOL. Therefore, we determined the SS pairings and succeeded in the chemical synthesis of highly pure NICOL, which is useful for the structural
Kenta Nagahama   +5 more
wiley   +1 more source

Breaking Bonds by Light: The Absorbance–Fragmentation Paradox

open access: yesChemistry – A European Journal, EarlyView.
Although octupolar and quadrupolar DMAQ‐derived probes showed superior ε and two‐photon absorption cross‐section (σ2) values relative to the dipolar one (1), the fragmentation efficiency exhibited inverse trend, and 1 emerged as the most effective caging group achieving Q = 12% quantum yield with σ2 = 86 GM and uncaging cross‐section δu = 10.2 GM at ...
Petra Dunkel   +8 more
wiley   +1 more source

Inhibition of the Clathrin Terminal Domain—Amphiphysin Protein–Protein Interaction. Probing the Pitstop 2 Aromatic Moiety

open access: yesChemMedChem, EarlyView.
Pitstop 2 binds to the clathrin terminal domain. This work explores the nature of the benzylidene moiety, R. The synthesis of 56 novel analogues reveals enhanced potency of a multiple analogues, with catechol‐free 2,3‐dihydroxybenzo[b][1,4]dioxone (54) returning a 1.2 μm IC50, ca 10‐fold more active than Pitstop 2. Pitstop 2, (Z)‐N‐(5‐(4‐bromenzylidene)
Kate Prichard   +10 more
wiley   +1 more source

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