A highly selective synthesis of an aldehyde‐functional polymonothiocarbonate (PMTC) was achieved through the copolymerization of a renewable‐sourced epoxide monomer and carbonyl sulfide. The epoxide monomer, derived from biomass‐based hydroxymethylfurfural (HMF) and epichlorohydrin (ECH), was produced in multigram quantities.
Mani Sengoden, Donald J. Darensbourg
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Design and characterisation of photoactivatable and lysine reactive <i>o</i>-nitrobenzyl alcohol-based crosslinkers. [PDF]
Cahill A+9 more
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Electrokinetic Manipulations Combined With Direct and Ambient Ionization Mass Spectrometry
ABSTRACT Mass spectrometry (MS) is a powerful analytical technique that typically involves sample preparation and online analytical separation before MS detection. Traditional methods often face bottlenecks in sample preparation and analytical separation, despite the rapid detection capabilities of MS.
Nicholas E. Manicke+2 more
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Michael Acceptor Compounds as Hemoglobin Oxygen Affinity Modulators for Reversing Sickling of Red Blood Cells. [PDF]
Mohammad KA+10 more
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The generation of the gem‐diol and hemiacetal forms using pyridine‐ and imidazole‐carboxaldehyde isomers in different chemical environments was studied by NMR spectra and combined with theoretical calculations. Unlike aprotic solvents, protic ones, as water and methanol, favored the generation of the gem‐diol and hemiacetal structures.
Ayelén F. Crespi+5 more
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A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles. [PDF]
Huang R+6 more
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To better understand how the biocatalyzed depolymerization of polyesters works, model molecules are needed to develop activity assays and determine enzymatic kinetic parameters. In this communication the chemical synthesis and characterization of 2‐hydroxyethyl furan‐5‐carboxylic acid and bis(2‐hydroxyethyl) furan‐2,5‐dicarboxylates as potential model ...
Francesco Raboni+6 more
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Applicability Domain of the Sens-Is In Vitro Assay for Testing the Skin Sensitization Potential of Rheology-Modifying Polymers. [PDF]
Hochar I+5 more
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Unprotected glycosyl pyridinium salts may be accessed in a single step from the corresponding unprotected sugar in aqueous solution. Whilst meta‐ and para‐substitution is well tolerated, ortho substitution of the N‐heterocycle inhibits product formation. Electrochemical studies revealed reduction potentials in the range of −0.9 to −1.4 V.
Daniel Chong+2 more
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Preliminary Investigation of GC-MS Profiling and Antibacterial Activities of Different Solvent Extracts From <i>Litchi chinensis</i> Sonn. Seed. [PDF]
Sharmin S+10 more
europepmc +1 more source