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Interfacial Structure-Determined Reaction Pathway and Selectivity for 5-(Hydroxymethyl)furfural Hydrogenation over Cu-Based Catalysts

ACS Catalysis, 2020
The catalytic upgrading of biomass-derived feedstocks to valuable chemicals generally requires catalysts with integrated active sites and tuned structures for selective activation of their multifun...
Qian Wang   +7 more
semanticscholar   +1 more source

Two-dimensional metal–organic framework nanosheets for highly efficient electrocatalytic biomass 5-(hydroxymethyl)furfural (HMF) valorization

Journal of Materials Chemistry A, 2020
2D metal–organic frameworks (MOFs) could promote biomass valorization, and electrooxidation of 5-(hydroxymethyl)furfural (HMF) into 2,5-furandicarboxylic acid (FDCA) with a highly efficient electrocatalytic performance.
Mengke Cai   +5 more
semanticscholar   +1 more source

Tetrakis(hydroxymethyl)phosphonium salts: Their properties, hazards and toxicities

Phosphorus Sulfur and Silicon and the Related Elements, 2020
Tetrakis(hydroxymethyl)phosphonium chloride (THPC) and sulfate (THPS) are of importance in the textile industry as flame retardants, in the oil industry as scale-removers, as biocides for water systems, in the leather industry as tanning agents, in ...
D. Moiseev, B. James
semanticscholar   +1 more source

Selective Hydrogenation of 5-Hydroxymethylfurfural into 2,5-Bis(hydroxymethyl)furan over a Cheap Carbon-Nanosheets-Supported Zr/Ca Bimetallic Catalyst

Energy & Fuels, 2020
Catalytic transfer hydrogenation (CTH) of 5-hydroxymethylfurfural (HMF) into 2,5-bis(hydroxymethyl)furan (BHMF) is an important way for the catalytic upgrading of biomass-derived platform compounds...
Junhua Zhang   +6 more
semanticscholar   +1 more source

Electrocatalytic Oxidation of 5-(Hydroxymethyl)furfural Using High-Surface-Area Nickel Boride.

Angewandte Chemie, 2018
The electrochemical oxidation of the biorefinery product 5-(hydroxymethyl)furfural (HMF) to 2,5-furandicarboxylic acid (FDCA), an important platform chemical for the polymer industry, is receiving increasing interest.
Stefan Barwe   +8 more
semanticscholar   +1 more source

ChemInform Abstract: Synthesis and Properties of (Hydroxymethyl)dimethylgermane and (Hydroxymethyl)diphenylgermane. [PDF]

open access: possibleChemInform, 1989
AbstractThe title compounds (VIII) are prepared from GeCl4 (I) by a four‐step synthesis.
B. Becker, R. Tacke
openaire   +1 more source

Hydroxymethylation of rhodanine

Russian Journal of General Chemistry, 2010
Rhodanine in alcohol solution reacts with formaldehyde aqueous solution to form 3-hydroxymethylrhodanine. In the presence of triethylamine occurred also bis-hydroxymethylation at 5 position of the thiazolidine ring, but we failed to isolate the 3,5,5-trishydroxymethyl derivative in an individual form.
S. Yu. Solov’eva   +3 more
openaire   +2 more sources

Syntheses and rearrangements of tris(hydroxymethyl)phosphine and tetrakis(hydroxymethyl)phosphonium salts

Phosphorus Sulfur and Silicon and the Related Elements, 2020
Tetrakis(hydroxymethyl)phosphonium (HOCH2)4P+ salts, particularly the chloride (THPC) and sulfate (THPS), are among the most accessible organophosphorus compounds that can be made quantitatively from PH3 and formaldehyde in aqueous media under ambient ...
D. Moiseev, B. James
semanticscholar   +1 more source

Aerobic Oxidation of 5-(Hydroxymethyl)furfural Cyclic Acetal Enables Selective Furan-2,5-dicarboxylic Acid Formation with CeO2 -Supported Gold Catalyst.

Angewandte Chemie, 2018
The utilization of 5-(hydroxymethyl)furfural (HMF) for the large-scale production of essential chemicals has been largely limited by the formation of solid humin as a byproduct, which prevents the operation of stepwise batch-type and continuous flow-type
Minjune Kim   +4 more
semanticscholar   +1 more source

Synthesis and Evaluation of Bio-Based Plasticizers from 5-Hydroxymethyl-2-Furancarboxylic Acid for Poly(vinyl chloride)

, 2020
5-hydroxymethyl-2-furancarboxylic acid (HFCA), a promising bio-monomer from renewable resources, was used to synthesize two bio-based plasticizers, namely HHMFC and DHOBFC.
Yanying Hao   +4 more
semanticscholar   +1 more source

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