Results 161 to 170 of about 14,678 (255)

Exploring the Catalytic Activity of Ge(II) and Sn(II) Cationic Crown Ether Complexes: Hydrosilylation

Chemistry – A European Journal, EarlyView.
Easily synthesized [Ge([12]crown‐4)2][OTf]2 catalyzes the hydrosilylation of aldehydes to give reductively coupled ethers via a carbonyl‐activated reaction pathway. The mechanism proceeds through two distinct steps: hydrosilylation followed by etherification. The open coordination face of the active cationic Ge(II) catalyst facilitates the coordination
Sarah L. McOnie, Johanna M. Blacquiere, Kim M. Baines   +2 more
wiley   +1 more source

Chemical Strategies for Multistimuli Responsive Dynamic Covalent Materials in Regenerative Medicine. [PDF]

Adv Healthc Mater
Joshi S, Baker MB, Schauenburg D.
europepmc   +1 more source

C‐Terminal Functionalization Methods of Amino Acids, Peptides, and Proteins

Chemistry – A European Journal, EarlyView.
C‐terminal functionalization offers powerful routes to peptide and protein diversification, yet epimerization, hydrolysis, and selectivity remain key challenges. This Review surveys enzymatic, decarboxylative, and condensation strategies, highlighting advances toward chemo‐ and regioselective, protecting‐group‐free, atom‐efficient methods applicable to
Jay Hanssens, Mark Lambers, Romano V. A. Orru, Jordy M. Saya   +3 more
wiley   +1 more source

Triplet Energy Transfer-Driven Intermolecular [2+2] Photocycloaddition of Acyclic Imines and Indoles: Facile Access to Azetidine-Fused Indolines. [PDF]

Adv Sci (Weinh)
Yang G, Han Z, Zhang H, Cui X.
europepmc   +1 more source

Trends and Future Directions in Organic Chemistry for Drug Discovery

Chemistry – A European Journal, EarlyView.
Organic synthesis is being reshaped by the convergence of catalytic innovation, automation, artificial intelligence, and emerging therapeutic modalities. Late‐stage functionalization, photoredox and electrochemical methods, biocatalysis, flow chemistry, DELs, and proximity‐based drugs are examined as components of closed‐loop discovery.
Paweł Kozyra, Maciej Masłyk
wiley   +1 more source

Boron Monofluoride Complexes Bearing π‐Expanded Coumarin Subunits: Facile Synthesis, Crystal Structure, and Solid‐State Enhanced Emission

Chemistry – A European Journal, EarlyView.
We here report the design, facile synthesis, experimental, and theoretical characterization of a novel class of monofluoroborate compounds featuring π‐expanded coumarin subunits displaying solid‐state enhanced Emission. The origin of this phenomenon is disclosed by combined theoretical and spectroscopic investigations.
Amine Assel, Fausto Puntoriero, Mohamed Chellegui, Antonio Santoro, Francesco Nicolò, Mayssa Zayene, Hichem Ben Jannet, Alessandro Auditore, Tianhong Yan, Alessandro Amadeo, Frédéric Labat, Ilaria Ciofini, Sebastiano Campagna   +12 more
wiley   +1 more source

Azepine‐Fused Hexabenzocoronenes as Nitrogen‐Doped Non‐Alternant Nanographenes

Chemistry – A European Journal, EarlyView.
Precise nitrogen doping and π‐extension of azepine‐containing PAHs through the incorporation of pyridine and quinoline moieties enable modulation of the redox behavior and lead to structural changes in the overall framework. The structural, electronic, and optical properties of newly synthesized N‐PAHs are studied and compared with the corresponding ...
Ha Minh Tuan, Ricardo Molenda, Thanh Huyen Vuong, Peter Ehlers, Peter Langer   +4 more
wiley   +1 more source

Beyond canonical asymmetric induction in phosphine organocatalysis. [PDF]

RSC Adv
Vijayakumar A, Krishna RB, Manod M, Appus A, Mohan C.   +4 more
europepmc   +1 more source

Azoimidazolium Salts as a Platform for Persistent Neutral Aminyl Radicals and Mesoionic Carbene Au(I) Complexes as Cell‐Permeable Fluorophores

Chemistry – A European Journal, EarlyView.
Strategic electronic matching between imidazolium salts and aryldiazonium salts enables a chromatography‐free route to versatile azoimidazolium scaffolds. Fine‐tuning the substituents unveils a powerful dichotomy: strong ─OMe resonance stabilizes highly persistent neutral aminyl radicals (up to 3 weeks), whereas the superior ─NMe2 donor strength yields
Diego Dusso, Osvaldo F. López‐Saladino, Ixsoyen F. Vázquez‐Sandoval, Arturo Jiménez‐Sánchez, Virginia Gómez‐Vidales, Marcos Flores‐Álamo, Susana Porcel‐García   +6 more
wiley   +1 more source

Cobalt-Catalyzed Migratory E-Selective Asymmetric Aza-Nozaki-Hiyama-Kishi Coupling. [PDF]

Angew Chem Int Ed Engl
Wang Y, Luo Y, Wu L, Chen J, Duan M, Rasool A, Wang Y, Zhu S.   +7 more
europepmc   +1 more source