Results 151 to 160 of about 14,359 (248)

Triplet Energy Transfer-Driven Intermolecular [2+2] Photocycloaddition of Acyclic Imines and Indoles: Facile Access to Azetidine-Fused Indolines. [PDF]

Adv Sci (Weinh)
Yang G, Han Z, Zhang H, Cui X.
europepmc   +1 more source

Modular Access to α‐Tertiary Amines: Electrochemical Tandem Di‐Functionalization of Olefins With Ammonia Surrogates and Amino Acids

Angewandte Chemie, EarlyView.
A metal‐ and oxidant‐free electrochemical multicomponent di‐functionalization strategy that rapidly converts 1,1‐disubstituted alkenes into α‐tertiary primary amines with simultaneous installation of bio‐relevant sulfur or selenium motifs was devised for late‐stage functionalization. ABSTRACT Quaternary carbon centers, especially those bearing nitrogen,
Adrija Ghosh, Tarun, Sven Erik Peters, Lutz Ackermann, Debasis Banerjee   +4 more
wiley   +1 more source

The Staudinger reaction: a versatile synthetic tool for the construction of β-lactams, heterocycles, and functional organic molecules. [PDF]

RSC Adv
Mughal EU, Naeem N, Iftikhar L, Shabnam, Afzaal A, Alrafai HA, Zaki MEA, Sadiq A, Fathalla M.   +8 more
europepmc   +1 more source

Nitrogen Radical Photocatalysed Reduction of Nitrous Oxide

Angewandte Chemie, EarlyView.
This work offers the first example of reduction of the potent greenhouse gas N2O to the benign products N2 and O(Bpin)2 using a nitrogen‐based catalyst. The active catalyst is shown to be a nitrogen‐based radical which operates under photocatalytic conditions.
Reece Lister‐Roberts, Agamemnon E. Crumpton, Meera Mehta   +2 more
wiley   +1 more source

High-entropy photocatalyst enabling collaborative cascade C-N coupling for converting benzyl alcohol to imine. [PDF]

Nat Commun
Yang N, Shu Y, Chen Z, Cao Z, Cao H, Ye S, Xiong Y.   +6 more
europepmc   +1 more source

Ruthenium‐Catalyzed Nitrile‐Acrylate Reductive Coupling by 2‐Propanol: Synthesis of Enantioenriched β‐Amino Esters

Angewandte Chemie, EarlyView.
The first nitrile reductive couplings beyond stoichiometric metals or metalloids are described. Using a ruthenium catalyst derived from RuHCl(CO)(PPh3)3 and Cy‐BIPHEP, 2‐propanol‐mediated reductive coupling of phenyl acrylate with aromatic or aliphatic nitriles delivers α,β‐unsaturated β‐amino esters.
Sebastian Höthker, Colin E. Hayter, Weijia Shen, Michael J. Krische   +3 more
wiley   +1 more source

Cobalt-catalyzed asymmetric three-component reductive addition of alkynes with alkyl halides and imines. [PDF]

Nat Commun
Hou L, Wu W, Wang Z, Wu X, Qu J, Chen Y.
europepmc   +1 more source

Oxidative Coupling of Alcohols and Amines Using Functionalized Cu(II) 2‑Quinoxolinol Salen Catalysts. [PDF]

ACS Omega
Huo X, Hicks R, Chugh A, Guragain B, Gorden JD, Gorden AEV.   +5 more
europepmc   +1 more source

Unified Synthesis of Unconventional α‐Polyhalogenated Amines Through Hydroaminoalkylation

Angewandte Chemie International Edition, EarlyView.
A unified, redox‐neutral method that transforms alkenes and alkynes into α‐polyhalomethyl amines using stable hemiaminal reagents is reported. This approach enables access to CF3, CF2H, CF2Cl, and CFClH motifs, expanding halogenated amine space with broad substrate scope, functional group tolerance, and applicability to late‐stage modification of drug ...
Angela K. Hofmeister, Giulia Iannelli, Péter Angyal, Augustin Malandain, Daniel Kaiser, Boris Maryasin, Hanspeter Kählig, Matteo Barel, Gaia Novarino, Nuno Maulide   +9 more
wiley   +1 more source

Design, Synthesis, and Biological Evaluation of Trifluoromethylated 1,2,4-Triazin-6-ones with Selective Antimycotic Activity and Hormesis Effects. [PDF]

Int J Mol Sci
Kowalczyk A, Trębska A, Sęczkowska M, Gach-Janczak K, Ciesielska A, Stączek P, Jasiński M.   +6 more
europepmc   +1 more source