Results 171 to 180 of about 14,359 (248)

Catalytic Sulfur‐Atom Transfer Enabled by a Bis(disulfide) Titanium Complex

open access: yesAngewandte Chemie International Edition, EarlyView.
Multi‐electron transformations with titanium are underexplored due to limited access to low‐valent precursors. The four‐electron activation of elemental sulfur by a Ti(IV) complex yields a rare titanium bis(disulfide) complex, enabling the efficient catalytic synthesis of isothiocyanates from isonitriles under mild conditions.
Sebastian Samir Cremer   +3 more
wiley   +1 more source

Covalent Protein Inhibitors via Tyrosine and Tryptophan Conjugation with Cyclic Imine Mannich Electrophiles. [PDF]

open access: yesAngew Chem Int Ed Engl
Wang S   +6 more
europepmc   +1 more source

Solvent-Free Synthesis of Chiral Substituted <i>N</i>‑Benzylideneanilines Imines: X‑ray Structure, and DFT Study. [PDF]

open access: yesACS Omega
Hernández Téllez G   +7 more
europepmc   +1 more source

Unlocking the reactivity of difluoroketene and its synthetic applications. [PDF]

open access: yesNat Commun
Xi S   +10 more
europepmc   +1 more source

Peptide Thioester and Triazole Derivatives Through On‐Resin Dual‐Modification of Peptide Thiosulfonates

open access: yesAngewandte Chemie International Edition, EarlyView.
An on‐resin dual‐modification strategy for peptides is presented, comprising S‐alkynylation of peptide thiosulfonates and regioselective iridium‐catalyzed azide–thioalkyne cycloaddition. This method reliably provides access to peptides with intricate non‐canonical modifications, being compatible with complex peptides, alkynes and azides.
Marius Werner   +5 more
wiley   +1 more source

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