Results 21 to 30 of about 26,685 (297)

Trifluoroethanol Promoted Castagnoli–Cushman Cycloadditions of Imines with Homophthalic Anhydride

open access: yesMolecules, 2022
Lactams are essential compounds in medicinal chemistry and key intermediates in the synthesis of natural products. The Castagnoli–Cushman reaction (CCR) of homophthalic anhydride with imines is an exciting method for accessing cyclic densely substituted ...
Thibault Bayles, Catherine Guillou
doaj   +1 more source

Imine Palladacycles: Synthesis, Structural Analysis and Application in Suzuki–Miyaura Cross Coupling in Semi-Aqueous Media

open access: yesMolecules, 2022
Treatment of the imines a–c with palladium(II) acetate in acetic acid yielded the μ-acetate dinuclear complexes 1a–c, which readily reacted with sodium chloride or bromide to provide μ-halide analogues.
Brais Bermúdez-Puente   +5 more
doaj   +1 more source

Imine-Enamine Tautomerism -Nucleophilic Reactions of Imines [PDF]

open access: yesZeitschrift für Naturforschung B, 1982
Abstract A reinvestigation of the reactivity of N-isopropylidene cyclohexylamine to methyl acrylate by GC-MS analysis has shown that the major product is the β-aminoester (9) formed by the N-alkylation of cyclohexylamine which may be generated by a dimerisation-elimination sequence.
Atta-ur Rahman   +4 more
openaire   +1 more source

Copper-Catalyzed Syntheses of 3‑Allyl-3-arylthioindolin-2-imines and 3‑Allenyl-3-arylthioindolin-2-imines from 3‑Diazoindolin-2-imines

open access: yes, 2018
3-Allyl-3-arylthioindolin-2-imines and 3-allenyl-3-arylthioindolin- 2-imines were synthesized via the copper-catalyzed reaction of 3-diazoindolin-2-imines with allyl and propargyl aryl sulfides, respectively.
Yanguang Wang (1412947)   +3 more
core   +2 more sources

Regioselective Mercury(I)/Palladium(II)-Catalyzed Single-Step Approach for the Synthesis of Imines and 2-Substituted Indoles

open access: yesMolecules, 2021
An efficient synthesis of ketimines was achieved through a regioselective Hg(I)-catalyzed hydroamination of terminal acetylenes in the presence of anilines.
Rsuini U. Gutiérrez   +4 more
doaj   +1 more source

Cobalt Catalyzed Enantioselective Reductive Coupling of Imines and Internal Alkynes

open access: yes, 2023
Chiral allylic amines hold significant importance as structural components in natural products, pharmaceuticals, and chiral catalysts. In this study, we have delved into cobalt-catalyzed enantioselective reductive coupling of imines with internal alkynes.
Biplab, Maji   +2 more
core   +1 more source

Solvent-free synthesis of azomethines, spectral correlations and antimicrobial activities of some E-benzylidene-4-chlorobenzenamines

open access: yesBulletin of the Chemical Society of Ethiopia, 2015
Some azomethines including substituted benzylidene-4-chlorobenzenamines (E-imines) have been synthesized by fly-ash: PTS catalyzed microwave assisted condensation of 4-chloroaniline and substituted benzaldehydes under solvent-free conditions.
R. Suresh   +13 more
doaj   +1 more source

Experimental and Theoretical Studies on the Reactions of Aliphatic Imines with Isocyanates

open access: yes, 2023
In the context of a project aiming at the replacement of the 3-substituted β-lactam ring in classical β-lactam antibiotics by an N(3)-acyl-1,3-diazetidinone moiety, we have investigated the reaction of isocyanates with imines derived from allyl glycinate
Sereina, Riniker   +3 more
core   +1 more source

Direct Iminization of PEEK [PDF]

open access: yesMacromolecules, 2011
Semi-crystalline poly(ether ketone)s are important high-temperature engineering thermoplastics, but are difficult to characterize at the molecular level because of their insolubility in conventional organic solvents. Here we report that polymers of this type, including PEEK, react cleanly at high temperatures with low-volatility aralkyl amines to ...
Manolakis, Ioannis   +2 more
openaire   +1 more source

Tf2O‑Mediated Cyclization of α‑Acyl-β-(2-aminopyridinyl)acrylamides: Access to N‑Substituted 4H‑Pyrido[1,2‑a]pyrimidin-4-imines

open access: yes, 2020
A facile and efficient direct synthesis of N-substituted 4H-pyrido­[1,2-a]­pyrimidin-4-imines is developed from α-acyl-β-(2-aminopyridinyl)­acrylamides mediated by triflic anhydride (Tf2O) in the presence of 2-chloropyridine.
Ning Zhang (23771)   +7 more
core   +2 more sources

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