Results 191 to 200 of about 104,731 (310)

Redox‐Active Frustrated Lewis Pair‐Mediated B─H Bond Activation: From Proton Transfer to THF Ring Opening

open access: yesChemistryEurope, EarlyView.
Carbene‐stabilized dithiolene zwitterion, as a redox‐active frustrated Lewis pair, can mediate the B─H bond activation of catecholborane via hydride‐coupled reverse electron transfer processes. This discovery represents the first experimental evidence of the FLP‐mediated B─H activation via net proton transfer.
Yuzhong Wang   +5 more
wiley   +1 more source

Synthesis of the tricyclic indole alkaloids, dilemmaones A and B

open access: green, 2019
Katharine E. Lambson   +4 more
openalex   +2 more sources

Introducing the Cis‐2,3‐Bis(trifluoromethyl)cyclopropyl Chemotype: Late‐Stage Installation and Stereoelectronic Properties

open access: yesChemistryEurope, EarlyView.
The cis‐2,3‐bis(trifluoromethyl)cyclopropyl chemotype is introduced. The steric demand of this motif is intermediate between that of the heptafluoroisopropyl and prefluorotertbutyl groups; yet, it induces significantly less lipophilicity than these due to its facial polarity.
Daniel Gaviña   +5 more
wiley   +1 more source

Skeletal Editing from Pyridine to Aniline via C‐Insertion and N‐Isomerization

open access: yesChemistryEurope, EarlyView.
A concise protocol is presented that converts pyridines into anilines by externalizing the original pyridine nitrogen at either the "ipso" or "ortho" position, which results in para or meta‐primary aniline products. A key carbene‐insertion step precedes nitrogen migration, preserving both ring size and overall structure.
Yun Luo   +3 more
wiley   +1 more source

AASLD practice guidance on drug, herbal, and dietary supplement–induced liver injury

open access: yes, 2022
Hepatology, EarlyView.
Robert J. Fontana   +6 more
wiley   +1 more source

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