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In the presence of hexamethylphosphorous triamide, the reaction of isatin with arylidene pivaloylacetonitriles in dry methylene dichloride afforded functionalized spiro[cyclopropane-1,3′-indolines] in good yields and with high diastereoselectivity.
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N-(Cyanothioformyl)indoline; a new indoline ring forming reaction
Journal of the Chemical Society, Perkin Transactions 1, 1998Conversion of 2-hydroxymethyl- and 2-hydroxyethylaniline with Appel salt 1 into the arylimines 3 and 4 is accompanied by formation of the chloromethyl and chloroethyl derivatives 8 and 9. Triphenylphosphine converts compound 8 into the benzothiazine 6 but the chloroethyl compound 9 gives N-(cyanothioformyl)indoline 10 (55%) rather than the analogous ...
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The quantum yields of photodissociation and fluorescence of a solution of indoline in heptane were determined for various wavelengths. The quantum yield of photodissociation increases with increasing excitation energy.
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