Results 91 to 100 of about 33,147 (342)
The fire toxicity of polyurethane foams [Review] [PDF]
Polyurethane is widely used, with its two major applications, soft furnishings and insulation, having low thermal inertia, and hence enhanced flammability.
A Tewarson +63 more
core +1 more source
Chemical Methods for Peptide and Protein Backbone Cleavage
Protein cleavage plays essential roles in biology and is powerful for protein manipulation and functionalization as well as in recombinant expression and purification. Here, the historical background and most recent examples of chemical methods for protein and peptide backbone cleavage are discussed (part of the figure was generated in BioRender).
Miguel Angel Alena‐Rodriguez +1 more
wiley +1 more source
Catch and release’ cascades: a resin-mediated three-component cascade approach to small molecules [PDF]
The application of a ‘catch and release’ approach to palladium-catalysed multi-component cascade reactions leads to diverse libraries of pharmacologically interesting small molecules in high yield and with excellent ...
Andrew Cook +23 more
core +1 more source
The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank +6 more
wiley +1 more source
Isocyanate toughened pCBT: Reactive blending and tensile properties
Cyclic butylene terephthalate oligomers (CBT) were reacted in a ring-opening polymerization with three types of isocyanates: a bifunctional aromatic type, a bifunctional aliphatic type and a polymeric aromatic isocyanate.
T. Abt +3 more
doaj +1 more source
Three 2‐phosphinophenylaluminum dichloride complexes were synthesized and characterized as novel intramolecular FLPs. These FLP systems exhibit high Lewis acidity and effectively activate challenging substrates including aliphatic ketones, imines, and esters. DFT analysis revealed that strain release and Al–P dynamics govern their reactivity. Abstract (
Yoshihiro Nishimoto +2 more
wiley +1 more source
Development of thermally stable phosphonitrile elastomers for advanced aerospace structures [PDF]
Both high and low molecular weight, curable poly(fluoroalkoxy phosphazene) terpolymers were prepared. These terpolymers resulted from reaction of (Cl2PNn) polymer with alkoxides derived from CF3CH2OH and C3F7CH2OH, and an alkoxide derived from CH3CH(OH ...
Gerber, A. H. +3 more
core +1 more source
Automated synthesis of monodisperse oligomers, featuring sequence control and tailored functionalization [PDF]
Long, multifunctional sequence-defined oligomers were obtairred on solid support from a protecting-group-free two-step iterative protocol, based on the inherent reactivity of a readily available molecule containing an isocyanate and a thiolactone ...
Du Prez, Filip +4 more
core +4 more sources
Biobased non-isocyanate poly(carbonate-urethane)s of exceptional strength and flexibility
Dominik Wołosz, Paweł G. Parzuchowski
openalex +1 more source

