Results 11 to 20 of about 57,276 (400)

A Review of the Surface Modification of Cellulose and Nanocellulose Using Aliphatic and Aromatic Mono- and Di-Isocyanates

open access: yesMolecules, 2019
Nanocellulose has been subjected to a wide range of chemical modifications towards increasing its potential in certain fields of interest. These modifications either modulated the chemistry of the nanocellulose itself or introduced certain functional ...
Hatem Abushammala, Jia Mao
doaj   +2 more sources

Iron(II) catalyzed hydrophosphination of isocyanates [PDF]

open access: yesAngewandte Chemie, 2017
The first transition metal catalyzed hydrophosphination of isocyanates is presented. The use of low-coordinate iron(II) precatalysts leads to an unprecedented catalytic double insertion of isocyanates into the P-H bond of diphenylphosphine to yield ...
Blake, Alexander J.   +4 more
core   +3 more sources

Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(II) and Fe(II) m-terphenyl complexes [PDF]

open access: yesChemical Communications, 2016
Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild ...
Blake, Alexander J.   +6 more
core   +4 more sources

Fully Bio-Based Thermosetting Polyurethanes from Bio-Based Polyols and Isocyanates

open access: yesPolymers, 2021
The trend towards the utilization of bioresources for the manufacturing of polymers has led industry players to bring to the market new monomers. In this work, we studied 3 polyisocyanates and 2 polyols with high renewable carbon contents, namely L ...
Roberto Morales-Cerrada   +2 more
semanticscholar   +1 more source

Recent advances in compatibilization strategies of wood-polymer composites by isocyanates

open access: yesWood Science and Technology, 2020
Wood-polymer composites technologies are gaining more and more attention in the scientific community, positively affecting the increase in their industrial applications, for example, automotive, building, 3D printing, etc. Many research works are focused
A. Hejna   +5 more
semanticscholar   +1 more source

Polyurethanes and Polyallophanates via Sequence-Selective Copolymerization of Epoxides and Isocyanates.

open access: yesJournal of the American Chemical Society, 2020
Aryl isocyanates are introduced as comonomers for ring opening copolymerization (ROCOP) with epoxides. Informed by studies of reaction kinetics, we show that divergent sequence selectivity for AB- and ABB-type copolymers can be achieved with a single ...
Mark Jurrat   +4 more
semanticscholar   +1 more source

A versatile way for the synthesis of monomethylamines by reduction of N-substituted carbonylimidazoles with the NaBH4/I2 system

open access: yesBeilstein Journal of Organic Chemistry, 2022
An economical and versatile protocol for the one-pot synthesis of monomethylamines by reduction of N-substituted carbonylimidazoles with NaBH4/I2 in THF at reflux temperature is described. This method used no special catalyst and various monomethylamines
Lin Chen   +5 more
doaj   +1 more source

Isocyanates as Precursors to Biomedical Polyurethanes

open access: yesChemical Engineering Transactions, 2014
This work is a review of the main chemical properties of aliphatic and aromatic isocyanates and their advantages and disadvantages when used as precursors for polyurethane (PU) synthesis, to be applied as biomedical polyurethanes.
L. Gabriel   +4 more
doaj   +1 more source

Novel bio-based epoxy-polyurethane materials from modified vegetable oils – synthesis and characterization

open access: yeseXPRESS Polymer Letters, 2017
Presented research shows the results of a study on mechanical properties of materials obtained in the course of innovatory application of epoxidized vegetable oil in the synthesis of new bio-based epoxy resins, crosslinked with curing agents which are ...
A. Sienkiewicz, P. Czub
doaj   +1 more source

Increase of Exhaled Nitric Oxide (eNO) after Methylene Diphenyl Diisocyanate (MDI) Exposure in Isocyanate Workers with Bronchial Hyperresponsiveness

open access: yesAllergology International, 2005
Background: : Isocyanates have become one of the most important causes of occupational asthma in industrialized countries. Increased exhaled nitric oxide (eNO) levels have been shown to be associated with allergic airway inflammation.
Xaver Baur, Luba Barbinova
doaj   +1 more source

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