Results 171 to 180 of about 190,443 (343)

Unlocking Lactonase Enzymes as Biocatalysts for the Deracemization of Chiral γ‐Thiolactones

open access: yesAngewandte Chemie International Edition, Accepted Article.
Lactonases, a class of metalloenzymes that exhibit catalytic promiscuity, have been extensively studied from a biological perspective, yet their application as biocatalysts remains underexplored. In this study, we disclose the biocatalytic activity of lactonase enzymes in the hydrolysis and deracemization of chiral C3‐substituted‐γ‐thiolactones and the
Jingyue Wu   +7 more
wiley   +1 more source

Crystallization of L‐Cysteine in Heavy Water Induces Intrinsic Fluorescence

open access: yesAngewandte Chemie International Edition, Accepted Article.
Developing non‐invasive techniques that can probe how solvents modulate the nucleation pathways of bioorganic molecules in solution remains an active and open area of research. Herein, we investigate the crystallization of the amino acid L‐Cysteine and show that both the structure of the crystal and its intrinsic fluorescence can be drastically altered
Debarshi Banerjee   +10 more
wiley   +1 more source

ORIGIN OF THE CARBON SKELETONS OF ISOLEUCINE AND VALINE

open access: hybrid, 1951
E. L. Tatum, Edward A. Adelberg
openalex   +1 more source

Protein Synthesis in Locust-flight-muscle Sarcosomes [PDF]

open access: yes, 1966
Bronsert, U.   +5 more
core   +1 more source

Excess Branched-Chain Amino Acids Suppress Mitochondrial Function and Biogenic Signaling but Not Mitochondrial Dynamics in a Myotube Model of Skeletal Muscle Insulin Resistance

open access: yesMetabolites
Branched-chain amino acids (BCAA) are correlated with severity of insulin resistance, which may partially result from mitochondrial dysfunction. Mitochondrial dysfunction is also common during insulin resistance and is regulated in part by altered ...
Lindsey R. VanDerStad   +2 more
doaj   +1 more source

Cooperative Photometallobiocatalysis: Nonheme Fe‐Enzyme‐Catalyzed Enantioconvergent RadicalDecarboxylative Azidation, Thiocyanation and Isocyanation of Redox‐Active Esters

open access: yesAngewandte Chemie International Edition, Accepted Article.
Cooperative catalysis with an enzyme and a smallmolecule photocatalyst has very recently emerged as a potentially general activation mode to advance novel biocatalytic reactions with synthetic utility. Herein, we report cooperative photobiocatalysis involving an engineered nonheme Fe enzyme and a tailored photoredox catalyst as a unifying strategy for ...
Yang Yang   +8 more
wiley   +1 more source

Isoleucine and Valine Metabolism in Escherichia coli

open access: hybrid, 1958
H. E. Umbarger, Barbara Brown
openalex   +1 more source

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