Results 91 to 100 of about 15,268 (209)
Abstract Emissions of nitrogen oxides (NOx = NO + NO2), a precursor to ozone and secondary aerosol formation have become increasingly important to understand as ozone production transitions to NOx limited in most regions of the US. Recent studies suggest that NOx emissions associated with agricultural activities, particularly cropland soils, are an ...
Ilana B. Pollack +28 more
wiley +1 more source
A nickel‐catalyzed three‐component reaction between arylaldehydes, butadiene, and malonates is developed yielding high functionalized homoallylic alcohols in a single step. No additional base is required and the reaction shows broad substrates compatibility with yields up to 96% and an exclusive selectivity toward the linear E‐isomer.
Anthony Saint Pol +7 more
wiley +1 more source
Abstract Plumes from sulfur dioxide (SO2) point sources have been shown to be significant contributors to new particle formation (NPF), but SO2 emissions in the United States (US) have decreased drastically by ∼10× since the early 2000s. We present observations of plume‐scale NPF from SO2 point sources over the industrial hub in Gary, Indiana and ...
En Li +27 more
wiley +1 more source
A five‐enzyme chemoenzymatic synthesis of the insect‐repellent (4R,7R)‐zingiberene from the wild tomato (Solanum habrochaites) has been developed. This approach enabled the elucidation of the sesquiterpene synthase cyclization mechanism of (2Z,6Z)‐farnesyl pyrophosphate and bypasses classic biosynthetic constraints of prenyltransferase chain extension ...
Luke A. Johnson +6 more
wiley +1 more source
Simple calcium bis(amido) compounds are exceptionally potent hydrophosphination catalysts in DMSO solution. At ambient temperature or under irradiation, this catalyst successfully engages all manner of unsaturated substrates with primary and secondary phosphines with more than 100 examples of high conversion.
Moniruzzaman Moniruzzaman, Rory Waterman
wiley +1 more source
A genome analysis revealed the presence of many bacterial‐type terpene synthases in springtails. Four enzymes from Sinella curviseta were functionally characterised, resulting in the isolation of several compounds including sinellene ether, the first diterpene ether identified from a terpene synthase that represents a novel skeleton.
Min Wang +5 more
wiley +1 more source
PyOrbb—Automated Analyses of Orbital‐Interaction Mechanisms
PyOrbb is an open‐source program that automates fragment‐based orbital interaction analysis from ADF calculations. It identifies the chemically most significant attractive and repulsive interactions and presents them as publication‐ready MO diagrams.
Yuman Hordijk +8 more
wiley +1 more source
Optimal seasonal schedule for the production of isoprene, a highly volatile biogenic VOC
The leaves of many trees emit volatile organic compounds (abbreviated as BVOCs), which protect them from various damages, such as herbivory, pathogens, and heat stress.
Yoh Iwasa, Rena Hayashi, Akiko Satake
doaj +1 more source
El Niño drought and heat extremes suppress soil isoprene uptake capacity in the Amazon rainforest
Soils are recognized sinks for atmospheric isoprene, but their in situ behavior remains understudied, particularly in the Amazon where emissions are globally significant.
Giovanni Pugliese +13 more
doaj +1 more source
Process Simulation of Isoprene Recovery from Dilute Fermentation Off-Gas Using Absorption-Desorption. [PDF]
Karim MF, Deo M.
europepmc +1 more source

