Results 51 to 60 of about 1,565,546 (166)
The nickel‐catalyzed S═NH N‐arylation of sulfonimidamides is described, with useful demonstrated substrate scope involving inexpensive and widely available (hetero)aryl chloride reaction partners, including the active pharmaceutical ingredient chlorpromazine.
Samuel A. Fisher +2 more
wiley +1 more source
TPET‐F2CN CMP exhibited higher CO2 uptake (2.88 mmol g−1 at 273 K) and superior Rhd B adsorption, with an equilibrium capacity of 98.12 mg g−1 and a maximum monolayer capacity of 155.6 mg g−1. ABSTRACT Herein, two conjugated microporous polymers (CMPs), TPET‐FO and TPET‐F2CN, are functionalized with carbonyl and nitrile groups.
Mohamed Gamal Mohamed +8 more
wiley +1 more source
Desorption isotherms and isosteric heat of araticum (Annona crassiflora Mart.) seeds [PDF]
The objective of this study was to determine the desorption isotherms and isosteric heat of Annona crassiflora Mart. seeds, using Akaike information criterion (AIC) and Schwarz’s Bayesian information criterion (BIC) to assist in the choice of the ...
Daniel E. C. de Oliveira +5 more
core +2 more sources
Sorption isosteric heat for some medicinal and aromatic plants
In this study, sorption isosteric heat for some medicinal and aromatic plants was determined by the application of the Clausius-Clapeyron equation to sorption isotherms.
Soysal Y., Öztekin S.
core +1 more source
The isosteric heat of adsorption is an important thermodynamic property used to characterise and optimise adsorption processes. In this work, analytic expressions for isosteric heats of adsorption are derived for a collection of commonly used isotherm ...
Ortiz, Jordan J. +7 more
core +1 more source
Ru‐based square‐grid metal–organic frameworks undergo dramatic conductivity enhancements after chemical oxidation. The mixed‐valent states exhibit the highest conductivity values, which correlate with the appearance of intervalence charge transfer bands.
Wang Zhang +12 more
wiley +1 more source
In order to study influence of temperature and pressure on gas adsorption and desorption characteristics of coal sample, adsorption capacity, isosteric heat of adsorption, Langmuir adsorption constant, initial effective diffusion coefficient and ...
XIA Hui, CAI Feng, YUAN Yuan, XU Chao
doaj +1 more source
Preserving Hierarchical Integrity During Primary Structure Modification of Spherulitic MOFs
A MOF‐74‐type zinc framework self‐organizes into well‐defined spherulitic superstructures while allowing precise covalent post‐synthetic modification (PSM) of the linkers. A built‐in tetrazine enables fast inverse electron‐demand Diels–Alder (iEDDA) functionalization to uniformly install primary amines.
Gabriela Kowacz +2 more
wiley +1 more source
Determination of isosteric heat of adsorption by quenched solid density functional theory
The heat of adsorption is one of the most important parameters characterizing energetic heterogeneity of the adsorbent surface. Heats of adsorption are either determined directly by calorimetry or calculated from adsorption isotherms measured at ...
Neimark, A.V. +3 more
core +2 more sources
The results of adsorption isotherm measurements for ethylene on purified HiPco SWNTs conducted at 11 different temperatures (between 110 K and 220 K) are reported, together with a comparison with the results we have obtained for ethane on the same ...
Dinesh S. Rawat, Aldo D. Migone
doaj +1 more source

