Results 101 to 110 of about 27,362 (303)

Radiation‐Resistant Kr‐Selective MOF With Record Kr/Xe Selectivity at Elevated Pressure

open access: yesAdvanced Science, EarlyView.
ABSTRACT The separation of Kr/Xe from spent nuclear fuel off‐gas is critical, yet most current adsorbents exhibit Xe‐Kr co‐adsorption under elevated pressures, posing challenges for industrial pressure swing adsorption processes. Herein, we present and evaluate a metal‐organic framework, CALF‐20M‐w, engineered for molecular sieving separation of Kr/Xe ...
Qihang Tian   +6 more
wiley   +1 more source

(Carbon isotope fractionation inplants)

open access: yes, 1990
The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation ...
O'Leary, M. H.
core   +1 more source

Nanoscale Secondary Ion Mass Spectrometry for Quantifying Membrane Fouling: Fouling Layer Structure and Chemical Interaction

open access: yesAdvanced Science, EarlyView.
Nanoscale secondary ion mass spectrometry (Nano SIMS) is established as a powerful analytical tool to visualize and quantify the membrane fouling layers. ABSTRACT Membrane technology has garnered considerable attention for applications in wastewater treatment and resource recovery. Nevertheless, membrane fouling remains a major barrier, yet the lack of
Mengfei Wu   +4 more
wiley   +1 more source

Copper Isotope Fractionation during Complexation with Insolubilized Humic Acid

open access: yes, 2016
The bioavailability, mobility, and toxicity of Cu depend on Cu speciation in solution. In natural systems like soils, sediments, lakes, and river waters, organo-Cu complexes are the dominating species.
Stefan Weyer (756611)   +2 more
core   +1 more source

Carbon isotopic fractionations during Fischer-Tropsch synthesis

open access: yesPetroleum Exploration and Development, 2011
To understand the carbon isotope fractionation during the mineral-catalyzed Fischer-Tropsch synthesis of hydrocarbons under hydrothermal conditions, experiments on formic acid were carried out at 300°C and 35 MPa using gold tubes in the presence of Fe as
Yunyan Ni, Yongbin Jin
doaj   +1 more source

Bioinspired Interfacial Hydration Engineering via Metal–Organic Frameworks for Efficient Nitrate‐To‐Ammonia Conversion in Neutral Media

open access: yesAdvanced Science, EarlyView.
Inspired by Nitrite reductase, a metal–organic framework overlayer is introduced to regulate the interfacial hydration microenvironment on Cu electrodes, enriching hydrated K+ species that act as efficient proton donors. This strategy enables nitrate‐to‐ammonia conversion with near‐unity selectivity at industrial‐level current densities in neutral ...
Yuyin Mao   +4 more
wiley   +1 more source

Revisiting Target‐Aware de novo Molecular Generation with TarPass: Between Rational Design and Texas Sharpshooter

open access: yesAdvanced Science, EarlyView.
TarPass provides a rigorous benchmark for target‐aware de novo molecular generation by jointly evaluating protein‐ligand interactions, molecular plausibility, and drug‐likeness on 18 well‐studied targets. Results show that current models often fail to consistently surpass random baseline in target‐specific enrichment, while post hoc multi‐tier virtual ...
Rui Qin   +11 more
wiley   +1 more source

ISOLUTION 1.0: an ISOtope evoLUTION model describing the stable oxygen (δ18O) and carbon (δ13C) isotope values of speleothems

open access: yesInternational Journal of Speleology, 2019
Stable oxygen and carbon isotope ratios (δ13C and δ18O) are the most applied climate and environmental proxies in speleothems allowing to infer past changes in cave drip water δ13C and δ18O related to climate and environmental variations from above the ...
Michael Deininger, Denis Scholz
doaj   +1 more source

A New Customizable Surfactant LLPS Strategy for Sustainable and Highly Efficient Radioactive Metal Ion Separation

open access: yesAdvanced Science, EarlyView.
A diluent‐free, customizable liquid–liquid phase separation (LLPS) platform enables highly efficient radioactive metal ion extraction and stripping. By encapsulating hydrophobic extractants into an ionic surfactant‐rich condensed phase, this LLPS system leverages synergistic electrostatic and coordination interactions.
Ruihan Yan   +7 more
wiley   +1 more source

Perspectives for the Study of 18O Isotope Effects of Enzymatic Phosphoryl Transfer Reactions by ESI-Orbitrap MS

open access: yesCHIMIA
Isotope effects play an important role in investigating enzymatic phosphoryl transfer reactions, which are central in biochemical pathways and environmental metabolism. However, resolving different isotope effects for mechanistic insights into phosphoryl
Nora M. Bernet, Thomas B. Hofstetter
doaj   +1 more source

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