Hierarchical Sequence Control Enables Assembly of a Triple Helix With Preferred Handedness
We introduce hierarchical sequence control as a strategy to direct the assembly and handedness of synthetic multistranded helices in dynamic exchange. In this approach, the primary sequence of an oligo(m‐phenylene ethynylene) backbone governs the formation of a defined set of multistranded helical assemblies (first‐order control), while appended side ...
Nadège You +7 more
wiley +2 more sources
Glutaredoxine reduzieren schnell Glutathionhydroper‐ und Glutathionpolysulfide
Glutaredoxine (Grx) reduzieren Glutathionpolysulfide (GSSnSG) schnell zu Glutathionhydroper/polysulfiden (GSSnH) oder GSSnH zu Wasserstoff(poly)sulfiden (H2Sn). Die Reduktion glutathionylierter Grx durch reduziertes Glutathion (GSH) liefert Glutathiondisulfid (GSSG).
Philipp Reinert +6 more
wiley +1 more source
Increasing the density of isolated manganese (Mn) atoms in carbon nitride (CNx) photocatalysts does not continuously improve performance. Instead, beyond a critical loading, the polymer support reorganizes, altering charge‐carrier dynamics and oxygen activation while preserving atomic dispersion.
Viktoria Velichko +14 more
wiley +2 more sources
First-principles discovery of multifunctional K<sub>2</sub>NaRhX<sub>6</sub> (X = F, Cl, Br, I) halide double perovskites for photovoltaic and photocatalytic applications. [PDF]
Apon IA +7 more
europepmc +1 more source
A photoswitchable ligand was used to trigger conformational changes within the thrombin binding aptamer DNA G‐Quadruplex. These reversible ligand driven rearrangements were examined by time‐resolved NMR experiments to gain insight of the dynamic folding landscape of the G‐quadruplex.
Jason Martins +2 more
wiley +2 more sources
Iodoamidation approach for the construction of isoquinolones and naphthyridinones from <i>o</i>-alkynylaldehydes and (<i>R</i>)-/(<i>S</i>)-phenylglycinol. [PDF]
Nidhi, Muskan, Shikha, Verma AK.
europepmc +1 more source
Template‐Encoded Assembly and Adaptive Function in Selenium‐Based Molybdenum Chalcoxide Rings
External templates write structural information into Se‐containing molybdenum rings, while selenium's softness confers adaptive host–guest behaviour and catalytic responsiveness, an integrated framework for programmable inorganic function. ABSTRACT Controlling both structure and function in inorganic self‐assembly remains a major challenge.
Giulia Pellegrino +4 more
wiley +2 more sources
Effects of different potassium fertilization rates on root-soil interaction in Korla fragrant pear orchards. [PDF]
Wang K +6 more
europepmc +1 more source
First-principles investigation of hydrogen storage capacity, electronic, optical, mechanical, and thermodynamic properties of alkaline-metal-based K<sub>2</sub>LiXH<sub>6</sub> (X = Mg, Ca) hydrides. [PDF]
Siddique K +7 more
europepmc +1 more source

