Results 71 to 80 of about 140,146 (333)

Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H2O2 Production via Data Science

Advanced Materials, EarlyView.
Metal‐free carbon catalysts enable the sustainable synthesis of hydrogen peroxide via two‐electron oxygen reduction; however, active site complexity continues to hinder reliable interpretation. This review critiques correlation‐based approaches and highlights the importance of orthogonal experimental designs, standardized catalyst passports ...
Dayu Zhu, Hsi‐wen Wu, Xiao Wang, Jie Zhang   +3 more
wiley   +1 more source

Contribution of microscopy for understanding the mechanism of action against trypanosomatids [PDF]

, 2018
Transmission electron microscopy (TEM) has proved to be a useful tool to study the ultrastructural alterations and the target organelles of new antitrypanosomatid drugs.
A Martinez-Palomo, A Montalvetti, A Rassi, AB Penissi, AE Eakin, AH Kolien, AJ Solari, AM Sánchez, Ana Yecê das Neves Pinto, C Brack, CF Silva Da, D Gonzalez-Pacanowska, DA Campbell, DA Johnston, DJ Hammond, DV Andrade, E Bontempi, E Lozano, E Lozano, E Lozano, EO Ogbadoiyi, ES Garcia, ES Lozano, F Dos Reis, FR Opperdoes, FR Opperdoes, FR Opperdoes, FS Laranja, H Meyer, H Meyer, J Aldunate, J Lukes, J McKerrow, J Mottram, JA Urbina, JA Urbina, JA Urbina, JA Urbina, JC Engel, JC Linder, JCP Dias, JCP Dias, JD Bergstrom, JD Maya, JF Turrens, JJ Marr, JL Avila, JL Avila, Juliano de Toledo, K Lazardi, K Miranda, K Miranda, KH Lee, L Simpson, LV Muschietti, M Meirelles, M Nieto, MC Elias, MCQB Elias, MR Ariyanayagam, MR Ariyanayagam, NM Sayed El, O Campetella, OS Giordano, OS Giordano, P Barrera, P Webster, PF Pimenta, R Docampo, S Sepúlveda-Boza, SD Brengio, SR Wilkinson, T Souto-Padron, T Souto-Padron, T Souto-Padron, T Souto-Padron, TA Shapiro, TS Tiuman, V Jimenez-Ortiz, V Sülsen, VP Sülsen, VP Sülsen, VV Costantino, W Souza De, W Souza De, W Souza De, W Souza De, W Souza De, W Souza De, Wanderley de Souza, WE Gutteridge   +90 more
core   +1 more source

Advancing Methylene Blue Adsorption Approach for More Precise Measurement of Specific Surface Area of Graphene Oxide

Advanced Materials Interfaces, EarlyView.
Looking for a faster, cheaper way to measure surface area in graphene oxide (GO)? This refined single‐point spectrophotometric methylene blue adsorption method‐optimized for concentration, adsorption time, and methylene blue/graphene oxide ratiooffers a rapid, reliable, and low‐cost surface area characterization of GO.
Pei Lay Yap, Deyu Wang, Dusan Losic
wiley   +1 more source

Secalonic acid A from Pseudoparmelia sphaerospora (Nyl.) Hale and P. hypomilta (Fée) Hale (Parmeliaceae) [PDF]

, 1995
Secalonic acid A, a yellow pigment from fungal metabolism, was isolated from the lichens Pseudoparmelia sphaerospora and P. hypomilta. From P. sphaerospora was also isolated the depsidone hypostictic acid.
Devincenzi, Izilda A. A., Filho, Lauro Xavier, Honda, Neli K.   +2 more
core   +1 more source

Diamond 2D/3D Printing Technology: Bringing Scintillating Performance to Functional Materials and Their Applications

Advanced Materials Technologies, EarlyView.
This review highlights advances in printing with nano‐ and microparticulate diamond for applications such as sensors, thermal management, machining tools, and biointerfaces. By covering screen, inkjet, microcontact, and 3D printing techniques, it outlines how diamond particles can be integrated into composite materials and functional devices, while ...
Simona Baluchová, Josephus G. Buijnsters   +1 more
wiley   +1 more source

Synthesis of Spirolactones from Carbonyls via Carboborylation of N‐Sulfonylhydrazones with Alkoxycarbonylalkylboronic Acids

Advanced Synthesis &Catalysis, EarlyView.
Spirolactones are readily prepared from carbonyls via their N‐tosylhydrazones. The reaction involves carboborylation with ethoxycarbonyl‐substituted boronic acids, followed by oxidation and lactonization. Thermal or photochemical protocols enable versatility.
Lucía López, Sara Filgueira, María‐Paz Cabal, Carlos Valdés   +3 more
wiley   +1 more source

Highly-functionalised difluorinated cyclohexane polyols via the Diels–Alder reaction : regiochemical control via the phenylsulfonyl group [PDF]

, 2005
A difluorinated dienophile underwent cycloaddition reactions with a range of furans to afford cycloadducts whichcould be processed regio- and stereoselectively via episulfonium ions, generated by the reaction between their alkenyl groups and ...
Crowley, Patrick J, Fawcett, John, Griffith, Gerry A, Moralee, Andrew C, Percy, Jonathan, Salafia, Vittoria   +5 more
core   +1 more source

Three‐Component Synthesis of γ‐Amino Esters with α‐Quaternary Carbon Centers via NHC/Photoredox Dual Catalysis

Advanced Synthesis &Catalysis, EarlyView.
γ‐Amino acid derivatives with an α‐quaternary center are prevalent in medicinally important compounds. A dual N‐heterocyclic carbene/photocatalytic pathway is developed for the three‐component synthesis of α, α ‐disubstituted γ‐amino esters. This methodology allows for the rapid synthesis of diverse libraries of γ‐amino esters in good yields.
Adam X. Wayment, Karl A. Scheidt
wiley   +1 more source

The stereochemistry of the Nozaki-Hiyama-Kishi reaction and the construction of 10-membered lactones. The enantioselective total synthesis of (-)-decarestrictine D

Journal of the Brazilian Chemical Society, 2001
The use of the intramolecular Nozaki-Hiyama-Kishi reaction to construct 10-membered lactones is described. The influence of the nature of the protecting groups at C4 and C5 on the stereochemistry of the newly formed stereogenic center at C7 was ...
Pilli Ronaldo A., Victor Mauricio M.
doaj  

Discovery of macrocyclic inhibitors of apurinic/apyrimidinic endonuclease 1 [PDF]

, 2019
Apurinic/apyrimidinic endonuclease 1 (APE1) is an essential base excision repair enzyme that is upregulated in a number of cancers, contributes to resistance of tumors treated with DNA-alkylating or -oxidizing agents, and has recently been identified as ...
Beglov, Dmitri, Brown, Lauren E., Chen, Qiujia, Chennamadhavuni, Spandan, Georgiadis, Millie M., He, Hongzhen, Kelley, Mark R., Panek, James S., Porco, John A., Reed, April, Trilles, Richard, Vajda, Sandor, Wireman, Randall   +12 more
core   +6 more sources