Researches on indoles. Part VIII. 3-hydroxymethyl indole-2-carboxylic acid lactone
Rita Harriet Harradence, Francis Lions
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Naturally Occurring Lactones and Lactames. III. The Absolute Configuration of the Hydroxycitric Acid Lactones: Hibiscus Acid and Garcinia Acid. [PDF]
Per M. Boll+7 more
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Recycling of Polyurethane via Mechanocatalytic Methanolysis/Hydrolysis
In this study, it is shown that up to 86% of soluble polyol can be recovered from the hydrolysis of polyurethane using a ball milling‐assisted process below 100 °C in the presence of NaOH, a small amount of H2O and a Cu/MgAlOx co‐catalyst. Polyurethane (PU) is the 6th most produced plastic on a global basis, and thus one of the most important targets ...
Bolun Wang+7 more
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Preparation of Optically Active γ- and δ-Lactones by Microbiological Reduction of the Corresponding Keto Acids [PDF]
G. Tuynenburg Muys+2 more
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The reversible derivation of the –CHO group of furfural with N,N‐Dimethylhydrazine not only restores the nucleophilicity of the furan ring toward formaldehyde but also opens an alternative mechanism to the classical acid‐catalyzed pathway for the selective hydroxymethylation of the furanic ring of furfural.
Sarah Behloul+4 more
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Zinc complexes of a new family of sequential {ONNN} ligands are introduced and employed for the ring‐opening polymerization of rac‐lactide. The pyridine‐amine‐imine‐phenolate complexes lead to a rare combination of very high activities and isoselectivities yielding stereomultiblock poly(lactic acid) while their isomers are less active and essentially ...
Inbar Kremer‐Shitrit+4 more
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Stereocontrolled synthesis of 3-hydroxy-2-piperidinone carboxamides by catalytic ring-opening aminolysis of bridged <i>δ</i>-lactam-γ-lactones. [PDF]
Beng TK+4 more
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From Spirocyclic Germanium Alkoxides to their Fluorido Germanates
Spirocyclic germanium salicyl alcoholates potentially meet the requirement as molecular precursors for twin polymerization, which is defined as a concerted formation of two polymeric materials from a so‐called twin monomer. Two examples of such germanium alkoxides and their associated fluorido germanates are reported and aspects of their chirality and ...
Philipp Kitschke+7 more
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Synthesis of bicyclo[3.2.0]heptane lactones <i>via</i> a ligand-enabled Pd-catalyzed C(sp<sup>3</sup>)-H activation cascade. [PDF]
Fan Z, Cai X, Sheng T, Yu JQ.
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The synthesis of biobased polyesters, including soluble polymer networks, displaying better tensile properties beyond polyolefins by adopting ADMET polymerization, and the post‐modification for preparation of the multiblock copolymers and the composite have been reviewed.
Mohamed Mehawed Abdellatif+1 more
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