Results 131 to 140 of about 46,706 (268)

Naturally Occurring Lactones and Lactames. III. The Absolute Configuration of the Hydroxycitric Acid Lactones: Hibiscus Acid and Garcinia Acid. [PDF]

open access: bronze, 1969
Per M. Boll   +7 more
openalex   +1 more source

Recycling of Polyurethane via Mechanocatalytic Methanolysis/Hydrolysis

open access: yesChemSusChem, Volume 18, Issue 12, June 17, 2025.
In this study, it is shown that up to 86% of soluble polyol can be recovered from the hydrolysis of polyurethane using a ball milling‐assisted process below 100 °C in the presence of NaOH, a small amount of H2O and a Cu/MgAlOx co‐catalyst. Polyurethane (PU) is the 6th most produced plastic on a global basis, and thus one of the most important targets ...
Bolun Wang   +7 more
wiley   +1 more source

N,N‐Dimethylhydrazine as a Reversible Derivatization Agent to Promote the Hydroxymethylation of Furfural with Formaldehyde

open access: yesChemSusChem, Volume 18, Issue 12, June 17, 2025.
The reversible derivation of the –CHO group of furfural with N,N‐Dimethylhydrazine not only restores the nucleophilicity of the furan ring toward formaldehyde but also opens an alternative mechanism to the classical acid‐catalyzed pathway for the selective hydroxymethylation of the furanic ring of furfural.
Sarah Behloul   +4 more
wiley   +1 more source

Highly Isoselective Polymerization of rac‐Lactide by Zinc Complexes of Sequential Tetradentate {ONNN} Ligands

open access: yesChemSusChem, EarlyView.
Zinc complexes of a new family of sequential {ONNN} ligands are introduced and employed for the ring‐opening polymerization of rac‐lactide. The pyridine‐amine‐imine‐phenolate complexes lead to a rare combination of very high activities and isoselectivities yielding stereomultiblock poly(lactic acid) while their isomers are less active and essentially ...
Inbar Kremer‐Shitrit   +4 more
wiley   +1 more source

From Spirocyclic Germanium Alkoxides to their Fluorido Germanates

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Spirocyclic germanium salicyl alcoholates potentially meet the requirement as molecular precursors for twin polymerization, which is defined as a concerted formation of two polymeric materials from a so‐called twin monomer. Two examples of such germanium alkoxides and their associated fluorido germanates are reported and aspects of their chirality and ...
Philipp Kitschke   +7 more
wiley   +1 more source

Acyclic Diene Metathesis Polymerization Approach for Synthesis of Biobased Polyesters: Summary of Recent Reports

open access: yesEuropean Journal of Lipid Science and Technology, EarlyView.
The synthesis of biobased polyesters, including soluble polymer networks, displaying better tensile properties beyond polyolefins by adopting ADMET polymerization, and the post‐modification for preparation of the multiblock copolymers and the composite have been reviewed.
Mohamed Mehawed Abdellatif   +1 more
wiley   +1 more source

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