Results 131 to 140 of about 15,069 (303)

Synergistic Regulation of Interfacial Potential and Anionic Covalency for High‐Voltage Cobalt‐Free All‐Solid‐State Batteries

Angewandte Chemie, EarlyView.
A synergistic interface regulation strategy using high‐dielectric BaTiO3 and sulfate‐derived S─O bonds is developed to unlock high‐voltage LiNi0.5Mn1.5O4 all‐solid‐state batteries. By mitigating space‐charge layer effects and stabilizing lattice oxygen, the system achieves high‐rate (3 C) and durable operation in 5 V‐class cobalt‐free solid‐state ...
Yue Wang, Shuibin Tu, Long Qian, Shijie Xu, Chao Ye, Shi‐Zhang Qiao   +5 more
wiley   +2 more sources

Silicon‐Based Anodes for Sulfide Solid‐State Batteries: Failure Mechanisms and Multiscale Design Strategies

Advanced Energy Materials, EarlyView.
Silicon anodes in sulfide SSBs face coupled electrochemo‐mechanical failure by interface instability. This review examined recent advances and proposed mitigation strategies via material‐, electrode/interface‐, and cell‐level‐ engineering. We further evaluate scalable synthesis of sulfide SEs.
Murugesan Karuppaiah, JaeWook Seo, SeEun Park, Seung Hyeok Chu, Jung Kyoo Lee   +4 more
wiley   +1 more source

High‐Performance Elastomeric Lithium Metal Anodes Enabled by a Lithiophilic Monolayer‐Assembled Nano‐Crumpled Micro‐Concave Architecture

Advanced Energy Materials, EarlyView.
We report an elastomeric lithium metal anode integrating hierarchical nano–micro architectures with uniformly assembled lithiophilic amine functionalities. This design enables synergistic stress and interfacial regulation, effectively suppresses dendritic growth, and ensures stable cycling, highlighting elastomeric anodes as a promising platform for ...
Sungha Choi, Donghyeon Nam, Geon Choi, Seonho Lee, Seungeun Paik, Yongkwon Song, Seungyeop Choi, Jaejin Lim, Woojae Chang, Jeong Gon Son, Daegun Kim, Giwon Lee, Sungjun Park, Yong Min Lee, Seoin Back, Yongmin Ko, Jinhan Cho   +16 more
wiley   +1 more source

Dynamical Aspects of Lithiation of a Nanosized Silicon Cluster

, 2016
Lithiation of silicon is attracting significant attention as a key technology in the development of next generation lithium-ion batteries. However, the large volume change associated with the lithiation is a roadblock to the practical use of silicon ...
Yasuharu Okamoto (1859821)
core   +1 more source

Molecular Design Strategies for High‐Voltage Organic Cathodes

Advanced Energy Materials, EarlyView.
This work proposes molecular engineering strategies for high‐voltage organic cathode materials for Li‐ion batteries: (1) increase Li‐O coordination number (CN), (2) achieve a greater increase in aromaticity upon reduction (∆Aromaticity), and (3) add an electron‐withdrawing group (EWG), through a combined experimental and computational study on reported
Sungil Hong, Alae Eddine Lakraychi, Artur Lyssenko, Abhishek Ashwin Panchal, Harshan Reddy Gopidi, Pieremanuele Canepa, Rafael Gómez‐Bombarelli, Yan Yao, Rajeev Surendran Assary   +8 more
wiley   +1 more source

Current‐Driven Li2O Formation in Catalyst‐Free Solid‐State Li‐O2 Batteries Enabling Simultaneous High Energy and High Power

Advanced Energy Materials, EarlyView.
A catalyst‐free solid‐state Li‐O2 battery achieves current‐driven four‐electron Li2O formation, delivering simultaneous high‐energy and high‐power operation with 1032 Wh·kg−1 and 374 W·kg−1 in a single cell. ABSTRACT Li‐O2 batteries offer a compelling pathway toward next‐generation energy storage owing to their ultrahigh theoretical energy density ...
Shu‐Ting Ko, Ziting Ma, Cruz Gonsalves, Joseph Degroot, Chuck Chunhu Tan, Timothy Lin, Cauê Nogueira, Xin Xu, Chunting Chris Mi, Lingping Kong   +9 more
wiley   +1 more source

A Study on Polymer Binders for High‐Capacity Silicon Anode: Effect of Prelithiation Precursors

Small Structures
While lithium‐ion batteries (LIBs) have advanced and are widely used, increasing energy density remains a significant challenge. Silicon (Si) has attracted attention as a next‐generation LIB anode material satisfying high energy density due to its high ...
Minju Song, Jongha Hwang, Junsu Son, Minji Park, Gyuri Kim, Nam‐Kyu Lim, Sanghyeon Woo, Tae Kyung Lee, Seulki Song, Woo‐Jin Song   +9 more
doaj   +1 more source

Leveraging the Amorphous Nature of Sn–P Alloys for Improved Stability and Energy Density in Na‐Ion Batteries

Advanced Energy Materials, EarlyView.
Amorphous SnP3 undergoes homogeneous solid‐solution sodiation, delivering exceptional cycling stability and volumetric capacity. In contrast, crystalline Sn4P3 phase‐separates into Na‐Sn and Na‐P domains, causing rapid capacity decay and severe pulverization.
Yixiang Zhang, Libin Zhang, Animesh Dutta, Ziwei Ye, Ben Tang, Michel Johnson, Nafiseh Zaker, Babak Shalchi‐Amirkhiz, Changlong Chen, J. R. Dahn, Chongyin Yang   +10 more
wiley   +1 more source

Colloidal Hot‐Injection Synthesis of CuBSe2 Nanocrystals: Tetragonal Chalcogenide Templates for Superionic Lithiation Pathways

Small Structures
Copper boron selenides represent a previously unexplored class of materials with tetragonal structural symmetries and bonding chemistries potentially relevant to lithium‐ion conduction.
Yunhao Xu, Niket Powar, Kelly Zervos, Isabella Campbell, Simran Choudhary, Layan Al‐Khaled, Progna Banerjee   +6 more
doaj   +1 more source

"High" Temperature Lithiation-trapping of Nitrogen and Oxygen Heterocycles [PDF]

, 2016
This thesis describes some novel aspects of the lithiation-trapping of nitrogen and oxygen heterocycles, including a systematic study of new methodologies at temperature above ‒78 °C and the use of the sustainable solvent, 2-MeTHF, as an alternative to ...
Kwong, Wai Sze Alice
core