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Rotaxanes with integrated photoswitches: design principles, functional behavior, and emerging applications [PDF]
Integrating molecular photoswitches into rotaxanes offers unique opportunities for precise control over their structural, dynamic, and functional properties.
Jullyane Emi Matsushima +4 more
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Reported here is the synthesis of a macrocycle with equatorial coordination sites for the construction of self-assembled metallacages. The macrocycle is prepared via a post-modification on the equator of biphen[n]arene.
Yibo Zhao +5 more
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Unprecedented synthesis of a 14-membered hexaazamacrocycle
The transformation of 3-[(ethoxymethylene)amino]-1-methyl-1H-pyrazole-4-carbonitrile into the 14-membered macrocycle, 2,10-dimethyl-2,8,10,16-tetrahydrodipyrazolo[3,4-e:3',4'-l][1,2,4,8,9,11]hexaazacyclotetradecine-4,12-diamine, by the reaction with ...
Anastasia A. Fesenko +1 more
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Chiroptical Sensing of Amino Acid Derivatives by Host–Guest Complexation with Cyclo[6]aramide
A hydrogen-bonded (H-bonded) amide macrocycle was found to serve as an effective component in the host–guest assembly for a supramolecular chirality transfer process.
Xuebin Wang +7 more
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Synthesis of Azacalixarenes and Development of Their Properties
This review focuses on the synthesis, structure, and interactions of metal ions, the detection of some weak interactions using the structure, and the construction of supramolecules of azacalixarenes that have been reported to date.
Hiroyuki Takemura
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Modulating the aggregation of amyloid proteins by macrocycles
The aggregation of amyloid proteins has been suggested to be the main cause of multiple human disorders; for example, amyloid β aggregates in Alzheimer's disease and α‐synuclein aggregates in Parkinson's disease.
Gao Li, Yan‐Mei Li
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The asymmetric unit of the title compound, C22H42N6·2CH4O, comprises one half of a 14-membered tetraazacyclotetradecane macrocycle with cyanoethyl substituents on one of the N atoms and a methanol solvent molecule.
Cheng-Jun Hao, Yan-Hua Zhang
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Симфонический макроцикл Ильи Хейфеца [PDF]
Статья посвящена симфоническому творчеству российского композитора И. Хейфеца, ныне живущего в Израиле. Автор предлагает рассматривать четыре его симфонии как единый макроцикл, внутри которого можно выделить два мини-цикла.
Жидяева, Галина Александровна
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A pH-Sensitive Peptide-Containing Lasso Molecular Switch
The synthesis of a peptide-containing lasso molecular switch by a self-entanglement strategy is described. The interlocked [1] rotaxane molecular machine consists of a benzometaphenylene[25]crown-8 (BMP25C8) macrocycle surrounding a molecular axle.
Karine Fournel-Marotte +2 more
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Macrocycles have attracted significant attention from academia due to their various applications in organic field-effect transistors, organic light-emitting diodes, organic photovoltaics, and dye-sensitized solar cells.
Chunxiao Zhong +9 more
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