Results 21 to 30 of about 6,769 (240)
“Texas-Sized” Molecular Boxes: From Chemistry to Applications
The design and synthesis of novel macrocyclic host molecules continues to attract attention because such species play important roles in supramolecular chemistry.
Xiaodong Chi +5 more
doaj +1 more source
Fluorenonophane chlorobenzene solvate: molecular and crystal structures
The title compound, 19H,79H-3,5,9,11-tetraoxa-1,7(2,7)-difluorena-4,10(1,3)-dibenzenacyclododecaphane-19,79-dione (fluorenonophane), exists as a solvate with chlorobenzene, C42H28O6·C6H5Cl.
Viktoriya V. Dyakonenko +4 more
doaj +1 more source
Glucopyranoside Recognition by Polypyridine-Macrocyclic Receptors Possessing a Wide Cavity with a Flexible Linkage [PDF]
New polypyridine-macrocyclic receptors for glucopyranosides were designed and synthesized. The artificial receptors possess a terpyridine skeleton as a hydrogen-bonding site and a flexible polyoxyethylene chain as a bridge for the macrocyclic structure ...
Hiroyuki Nakazumi (1679743) +2 more
core +1 more source
Traditional macrocyclic molecules encode recognition sites in their structural backbones, which limits the variation of the recognition sites and thus, would restrict the adjustment of recognition properties.
Linmeng Fan +4 more
doaj +1 more source
Tuning the Chiral Cavity of Macrocyclic Receptor for Chiral Recognition and Discrimination [PDF]
The size and shape of the chiral cavity of a macrocyclic receptor were tuned by the alteration of the binaphthyl moiety to improve the chiral recognition/discrimination ability. For example, host 3 with the 3,5-bis(trifluoromethyl)phenyl group at the 3,3′
Tadashi Ema (1581424) +3 more
core +1 more source
Resorcin[4]arenes (R[4]A) are macrocyclic compounds with a cavity structure. Despite a relatively small cavity, these compounds are capable of forming complexes with small organic molecules. The current paper focuses on the synthesis of complexes between
Waldemar Iwanek
doaj +1 more source
Uranium(III) Coordination Chemistry and Oxidation in a Flexible Small-Cavity Macrocycle [PDF]
U(III) complexes of the conformationally flexible, small-cavity macrocycle trans-calix[2]benzene[2]pyrrolide (L)2–, [U(L)X] (X = O-2,6-tBu2C6H3, N(SiMe3)2), have been synthesized from [U(L)BH4] and structurally characterized. These complexes show binding of the U(III) center in the bis(arene) pocket of the macrocycle, which flexes to accommodate the ...
Arnold, Polly L. +3 more
openaire +1 more source
Pseudopeptidic Macrocyclic Systems with Preorganized Cavities
Programa de Doctorat en Química ...
openaire +6 more sources
Molecular recognition using tetralactam macrocycles with parallel aromatic sidewalls
This review summarizes the supramolecular properties of tetralactam macrocycles that have parallel aromatic sidewalls and four NH residues directed into the macrocyclic cavity.
Dong-Hao Li, Bradley D. Smith
doaj +1 more source

