Results 21 to 30 of about 6,769 (240)

“Texas-Sized” Molecular Boxes: From Chemistry to Applications

open access: yesMolecules, 2021
The design and synthesis of novel macrocyclic host molecules continues to attract attention because such species play important roles in supramolecular chemistry.
Xiaodong Chi   +5 more
doaj   +1 more source

Fluorenonophane chlorobenzene solvate: molecular and crystal structures

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2021
The title compound, 19H,79H-3,5,9,11-tetraoxa-1,7(2,7)-difluorena-4,10(1,3)-dibenzenacyclododecaphane-19,79-dione (fluorenonophane), exists as a solvate with chlorobenzene, C42H28O6·C6H5Cl.
Viktoriya V. Dyakonenko   +4 more
doaj   +1 more source

Glucopyranoside Recognition by Polypyridine-Macrocyclic Receptors Possessing a Wide Cavity with a Flexible Linkage [PDF]

open access: yes, 2016
New polypyridine-macrocyclic receptors for glucopyranosides were designed and synthesized. The artificial receptors possess a terpyridine skeleton as a hydrogen-bonding site and a flexible polyoxyethylene chain as a bridge for the macrocyclic structure ...
Hiroyuki Nakazumi (1679743)   +2 more
core   +1 more source

Recognition Site Modifiable Macrocycle: Synthesis, Functional Group Variation and Structural Inspection

open access: yesMolecules, 2023
Traditional macrocyclic molecules encode recognition sites in their structural backbones, which limits the variation of the recognition sites and thus, would restrict the adjustment of recognition properties.
Linmeng Fan   +4 more
doaj   +1 more source

Tuning the Chiral Cavity of Macrocyclic Receptor for Chiral Recognition and Discrimination [PDF]

open access: yes, 2016
The size and shape of the chiral cavity of a macrocyclic receptor were tuned by the alteration of the binaphthyl moiety to improve the chiral recognition/discrimination ability. For example, host 3 with the 3,5-bis(trifluoromethyl)phenyl group at the 3,3′
Tadashi Ema (1581424)   +3 more
core   +1 more source

Complexes of resorcin[4]arene with secondary amines: synthesis, solvent influence on “in-out” structure, and theoretical calculations of non-covalent interactions

open access: yesBeilstein Journal of Organic Chemistry, 2023
Resorcin[4]arenes (R[4]A) are macrocyclic compounds with a cavity structure. Despite a relatively small cavity, these compounds are capable of forming complexes with small organic molecules. The current paper focuses on the synthesis of complexes between
Waldemar Iwanek
doaj   +1 more source

Uranium(III) Coordination Chemistry and Oxidation in a Flexible Small-Cavity Macrocycle [PDF]

open access: yesOrganometallics, 2015
U(III) complexes of the conformationally flexible, small-cavity macrocycle trans-calix[2]benzene[2]pyrrolide (L)2–, [U(L)X] (X = O-2,6-tBu2C6H3, N(SiMe3)2), have been synthesized from [U(L)BH4] and structurally characterized. These complexes show binding of the U(III) center in the bis(arene) pocket of the macrocycle, which flexes to accommodate the ...
Arnold, Polly L.   +3 more
openaire   +1 more source

Molecular recognition using tetralactam macrocycles with parallel aromatic sidewalls

open access: yesBeilstein Journal of Organic Chemistry, 2019
This review summarizes the supramolecular properties of tetralactam macrocycles that have parallel aromatic sidewalls and four NH residues directed into the macrocyclic cavity.
Dong-Hao Li, Bradley D. Smith
doaj   +1 more source

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