Results 41 to 50 of about 48,393 (330)

Total Synthesis of (+)‐Melonine and (+)‐N4‐Oxy Melonine Enabled by an Intramolecular Alkene Diamination Reaction

open access: yesAngewandte Chemie, EarlyView.
A complexity‐generating intramolecular alkene diamination constitutes the pivotal step in the enantioselective synthesis of the title natural products featuring a strained, cage‐like pentacyclic architecture. Abstract Among more than four thousand monoterpene indole alkaloids (MIAs) isolated to date, only a few feature a 2,2,3‐trisubstituted indoline ...
Vincent Goëlo, Qian Wang, Jieping Zhu
wiley   +2 more sources

Enantioselective Synthesis of Chiral Cyclopent‐2‐enones by Nickel‐Catalyzed Desymmetrization of Malonate Esters

open access: yesAngewandte Chemie, 2018
The enantioselective synthesis of highly functionalized chiral cyclopent‐2‐enones by the reaction of alkynyl malonate esters with arylboronic acids is described.
S. N. Karad   +4 more
semanticscholar   +1 more source

Electrochemical Perspective on Hematite–Malonate Interactions

open access: yesColloids and Interfaces, 2021
Organic matter (OM) interactions with minerals are essential in OM preservation against decomposition in the environment. Here, by combining potentiometric and electrophoretic measurements, we probed the mode of coordination and the role of pH-dependent ...
Karolina Kędra   +6 more
doaj   +1 more source

Crystal structure of poly[diaqua(μ-2-carboxyacetato-κ3O,O′:O′′)(2-carboxyacetato-κO)di-μ-chlorido-dicobalt(II)]

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2016
The asymmetric unit of the title polymer, [Co2(C3H3O4)2Cl2(H2O)2]n, comprises one CoII atom, one water molecule, one singly deprotonated malonic acid molecule (HMal−; systematic name 2-carboxyacetate) and one Cl− anion.
Yasmina Bouaoud   +5 more
doaj   +1 more source

Taming tosyl azide: the development of a scalable continuous diazo transfer process [PDF]

open access: yes, 2016
Heat and shock sensitive tosyl azide was generated and used on demand in a telescoped diazo transfer process. Small quantities of tosyl azide were accessed in a one pot batch procedure using shelf stable, readily available reagents. For large scale diazo
Collins, SG   +5 more
core   +1 more source

Synthesis, Thermal, Structural Analyses, and Photoluminescent Properties of a New Family of Malonate-Containing Lanthanide(III) Coordination Polymers

open access: yesFrontiers in Chemistry, 2019
Five new Lanthanide(III) complexes of malonic acid (HOOC-CH2-COOH); {[Gd(C3H2O4)(H2O)4]·NO3}n (1), {[Tb(C3H2O4)(H2O)4]·NO3}n (2), {[Ho(C3H2O4)(H2O)4]·NO3}n (3), [Er(C3H2O4)(C3H3O4)(H2O)2]n (4), and {[Eu2(C3H2O4)2(C3H3O4)2(H2O)6]·4H2O}n (5) were ...
Sajjad Hussain   +8 more
doaj   +1 more source

Biocatalytic Route to Chiral Precursors of β-Substituted-γ-Amino Acids [PDF]

open access: yes, 2011
In this work, we utilized commercial lipases (from Thermomyces lanuginosa, Rhizopus delemar, and Mucor miehei) as biocatalysts for the efficient synthesis of precursors of β-substituted-γ-amino acids.
Martinez, Carlos A., Mukherjee, Herschel
core   +2 more sources

Lack of continuity between Cronobacter biotypes and species as determined using multilocus sequence typing [PDF]

open access: yes, 2013
The accuracy of the Cronobacter biotyping scheme was compared with the 7-loci multilocus sequence typing scheme. Biotyping did not reliably assign species level identification, as only half (17/31) of the biotype variants were unique to any of the seven ...
Baldwin   +19 more
core   +1 more source

Malonate given at reperfusion prevents post-myocardial infarction heart failure by decreasing ischemia/reperfusion injury

open access: yesBasic Research in Cardiology
The mitochondrial metabolite succinate is a key driver of ischemia/reperfusion injury (IRI). Targeting succinate metabolism by inhibiting succinate dehydrogenase (SDH) upon reperfusion using malonate is an effective therapeutic strategy to achieve ...
J. Abe   +4 more
semanticscholar   +1 more source

Mass Spectra of 2-Substituted Diethyl Malonate Derivatives

open access: yesMolecules, 1999
Addition of Grignard derivatives to diethyl ethoxymethylene malonate generates 2-substituted diethyl malonate derivatives. This paper reports the mass spectral data for these derivatives.
Michael B. Smith   +2 more
doaj   +1 more source

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