Results 81 to 90 of about 48,393 (330)

Reactivity of (η3-allyl)dicarbonylnitrosyl iron complexes with dimethyl malonate and diisobutyl malonate

Bulletin of the Chemical Society of Ethiopia, 2017
In this paper, we describe the reactivity of our previously reported (η3-allyl)dicarbonylnitrosyl iron complexes (1–9). In this context, stoichiometric reactions of 1–9 with dimethyl malonate and di-iso-butyl malonate were carried out.
M. Tabassam, A. Farooq, M. Imran, S. R. Gillani, S. Saqib, Z. Mehmood, L. Mitu   +6 more
doaj   +1 more source

On the ordeal of quinolone preparation via cyclisation of aryl-enamines; synthesis and structure of ethyl 6-methyl-7-iodo-4-(3-iodo-4-methylphenoxy)-quinoline-3-carboxylate [PDF]

, 2017
Recent studies directed to the design of compounds targeting the bc(1) protein complex of Plasmodium falciparum, the parasite responsible for most lethal cases of malaria, identified quinolones (4-oxo-quinolines) with low nanomolar inhibitory activity ...
Bras, Elisa M., Cristiano, Maria De Lurdes, Fausto, Rui, Henriques, Marta S. C., Horta, Pedro, Murtinheira, Fernanda, Nogueira, Fatima, O'Neill, Paul M., Paixao, Jose A.   +8 more
core   +1 more source

Bioactive Phytochemical Compounds in Medicago sativa L. (Alfalfa): A Systematic Review of Biological Properties and Therapeutic Relevance in Nutraceutical and Functional Food Implications

Food Frontiers, EarlyView.
ABSTRACT Medicago sativa L. (alfalfa) harbors a remarkably diverse reservoir of bioactive secondary metabolites. Flavonoids, isoflavones, and triterpenoid saponins dominate its bioactivity landscape, driving potent antioxidant, anti‐inflammatory, antimicrobial, estrogenic, hypolipidemic, and cytotoxic actions through redox modulation, membrane ...
Parham Joolaei Ahranjani, Hamid Rashidi Nodeh, Zahra Esfandiari, Giovanna Ferrentino   +3 more
wiley   +1 more source

Synthesis and Reactivity of Tricarbonyl(1-ethoxy-carbonyl-2-methylpentadienyl)iron(1+) Cation [PDF]

, 2001
The title cation was prepared in two steps from the known (ethyl 3-methyl-6-oxo-2,4-hexadienoate)Fe(CO)3. Reation of the cation with NaBH3CN, methyl cuprate, phthalimide, water, PPh3, or malonate anions gave predominantly the products from nucleophilic ...
Bärmann, Heiko, Donaldson, William, Yun, Young K.   +2 more
core   +1 more source

Synthesis and Activity of Six-Membered Cyclic Alkyl Amino Carbene–Ruthenium Olefin Metathesis Catalysts [PDF]

, 2020
Ru–cyclic alkyl amino carbene (Ru–CAAC) olefin metathesis catalysts perform extraordinarily in metathesis macrocyclization and ethenolysis, but previous studies have been limited to the use of five-membered CAAC (CAAC-5) ligands.
Grubbs, Robert H., Samkian, Adrian E., Virgil, Scott C., Xu, Yan, Yoon, Ki-Young   +4 more
core  

Metabolomic profiles are gender, disease and time specific in the interleukin-10 gene-deficient mouse model of inflammatory bowel disease. [PDF]

, 2013
Metabolomic profiling can be used to study disease-induced changes in inflammatory bowel diseases (IBD). The aim of this study was to investigate the difference in the metabolomic profile of males and females as they developed IBD.
Churchill, Thomas A, Doyle, Jason, Fedorak, Richard N, Foshaug, Rae R, Slupsky, Carolyn M, Sydora, Beate C, Tso, Victor K   +6 more
core   +2 more sources

Electron Donor–Acceptor Complexes Without Preinstalled Sacrificial Leaving Groups: Applications in Synthesis

Helvetica Chimica Acta, EarlyView.
Leaving‐group–free electron donor–acceptor (EDA) complexes have emerged as a practical platform for photocatalyst‐free radical generation under visible light. This review highlights recent advances in coupling and cyclization reactions driven by such EDA complexes, emphasizing their atom‐economical and sustainable feature.
Wenheng Liu, Line Næsborg
wiley   +1 more source

A Radical Cascade with Double Intramolecular Hydrogen Atom Transfer for the Generation of Bisfunctionalized Cyclopentanes from Linear Alkynes

Angewandte Chemie, Volume 138, Issue 5, 28 January 2026.
A radical cascade process involving the activation of two aliphatic C–H bonds in a series of five elementary steps converts readily available terminal alkynes into functionalized cyclopentylmethyl arylsulfones. The methodology delivers flexible synthetic intermediates and was applied to the preparation of diquinanes and triquinanes possessing a rare ...
Lise Benoist, Éléonore Barbier, Mariam Sangare, Philippe Renaud, Fabrice Dénès   +4 more
wiley   +2 more sources

Polyoxometalate-intercalated layered double hydroxides as efficient and recyclable bi-functional catalysts for cascade reactions [PDF]

, 2016
The polyoxometalate (POM) intercalated-layered double hydroxides (LDHs) have been widely used as heterogeneous catalysts. However, the application of POM-LDHs as bi-functional catalysts for cascade reaction has seldom been studied comparing with the ...
Angelescu, Aronson, Chen, Chen, Chen, Climent, Corma, Dou, Farsani, Felpin, Finke, Fogg, Han, Iyi, Jiang, Kuroda, Kuwahara, Li, Liu, Liu, Liu, Mallik, Miras, Nakagawa, Neumann, Ramachary, Salvati, Taarning, Toma, Toyao, Wang, Wasilke, Xu, Yang, Yang, Yin, Yonehara, Zhang, Zhao, Zhao, Zhao, Zhu   +41 more
core   +1 more source

2,3‐Dichloro‐5,6‐Dicyano‐1,4‐Benzoquinone (DDQ)‐Mediated CC Bond Formation: Redox Strategies from Stoichiometric to Catalytic Systems

ChemistryOpen, EarlyView.
2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone serves as a versatile oxidant and redox catalyst for CC bond formation through hydride abstraction or single‐electron transfer. Stoichiometric and catalytic systems enable benzylic, allylic, and aromatic CH activation under mild, metal‐free conditions, providing sustainable routes to complex and bioactive ...
Dohoon Cha, Sun‐Joon Min
wiley   +1 more source