Structurally Defined Water‐Soluble Metallofullerene Derivatives towards Biomedical Applications
Angewandte Chemie International Edition, Volume 62, Issue 3, January 16, 2023., 2023 A modular metallobuckytrio (MBT) platform provides a family of structurally defined, water‐soluble metallofullerene derivatives that can safely carry rare‐earth elements in tailorable molecules, showing promise in biomedicines including MRI contrast agents and photosensitizers. Abstract Endohedral metallofullerenes (EMFs) are excellent carriers of rare‐
Yanbang Li +15 more
wiley +1 more source
Melaminium hydrogen malonate [PDF]
Acta Crystallographica Section E Structure Reports Online, 2012 The melaminium (2,4,6-triamino-1,3,5-triazin-1-ium) cation in the title compound, C3H7N6+·C3H3O4−, is essentially planar, with a r.m.s. deviation of the non-H atoms of 0.0085 Å. Extensive hydrogen bonding of the types N—H...N and N—H...O between cations and cations and between cations and hydrogen malonate (2-carboxyethanoate) anions leads to the ...
Matthias Weil, Barbara Froschauer
openaire +4 more sources
Asymmetric Organocatalysis-A Powerful Technology Platform for Academia and Industry: Pregabalin as a Case Study [PDF]
, 2022 Enantioselective organocatalysis has quickly established itself as the third pillar of asymmetric catalysis. It is a powerful technology platform, and it has a tremendous impact in both academic and industrial settings.
Bernardi, L +5 more
core +1 more source
A Three-Dimensional Dynamic Supramolecular "Sticky Fingers" Organic Framework. [PDF]
, 2019 Engineering high-recognition host-guest materials is a burgeoning area in basic and applied research. The challenge of exploring novel porous materials with advanced functionalities prompted us to develop dynamic crystalline structures promoted by soft ...
Costa, José Sánchez +8 more
core +6 more sources
Transition metal-free, visible light-mediated radical cyclisation of malonyl radicals onto 5-ring heteroaromatics [PDF]
, 2022 Annulated heteroaromatics can be accessed through the addition of malonyl radicals onto heterocycles. Current methods are applicable to electron-rich heteroaromatics and reliant on transition metals or toxic tin reagents.
Burton, Jonathan W +3 more
core +2 more sources
Time‐resolved multiparameter analytics on a cell‐free production platform for acyl‐CoA precursors
Analytical Science Advances, Volume 3, Issue 11-12, Page 289-296, December 2022., 2022 Abstract Cell‐free biosynthesis is emerging as a very attractive alternative for the production of market‐relevant molecules. The free combination of enzymes, regardless of where they are isolated from, raises the possibility to build more efficient synthetic routes but at the same time leads to higher complexity regarding the analysis of the different
Dominic Maehler +7 more
wiley +1 more source
Synthesis of novel β-aminocyclobutanecarboxylic acid derivatives by a solvent-free aza-Michael addition and subsequent ring closure [PDF]
, 2011 Novel beta-aminocyclobutanecarboxylic acid derivatives were prepared via a sequential solvent-free aza-Michael addition of benzophenone imine across 3-halopropylidenemalonates and base-induced ring closure.
Aitken +44 more
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Effect of Microwaves in the Chiral Switching Asymmetric Michael Reaction
Molecules, 2003 Highly enantioselective Michael reactions of malonates with cyclic enones are achieved in remarkably less time under microwave irradiation using newly developed heterobimetallic catalysts.
S. Velmathi, S. Narasimhan
doaj +1 more source
Molbank, 2023 This paper presents the discovery and development of antifungal agents against Fusarium oxysporum (Fox), a devastating plant pathogen. Diethyl 2-((arylamino)methylene)malonates (DAMMs) were formed as side-products during the synthesis of polysubstituted ...
Willy-Fernando Cely-Veloza +2 more
doaj +1 more source
Overturning established chemoselectivities : selective reduction of arenes over malonates and cyanoacetates by photoactivated organic electron donors [PDF]
, 2013 The prevalence of metal-based reducing reagents, including metals, metal complexes, and metal salts, has produced an empirical order of reactivity that governs our approach to chemical synthesis.
Asensio X. +52 more
core +1 more source