Chemistry – A European Journal, Volume 32, Issue 28, 25 July 2026.The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve +4 more
wiley +1 more source
A Hoveyda–Grubbs‐Type Olefin Metathesis Catalyst Bearing a Fluorinated Unsymmetrical NHC Ligand
European Journal of Inorganic Chemistry, Volume 29, Issue 21, 25 July 2026.A fluorinated unsymmetrical NHC ruthenium complex was synthesised and employed as a catalyst for olefin metathesis reactions. The modification of the steric and electronic properties of the NHC ligand through the introduction of fluorine substituents results in improved activity but lower selectivity compared to the analogous non‐fluorinated NHC ...
Rubina Troiano +3 more
wiley +1 more source
European Journal of Inorganic Chemistry, Volume 29, Issue 20, 17 July 2026.The lithium enediamide complex 2 with intrinsically inverted C–N bond polarity combines strong basicity with unusual reactivity: deprotonation of malonates enables C–C bond formation without electron transfer. Depending on malonate substitution, electrophilic substitution or addition occurs at the enediamide CC bond.
Muhan Liang +3 more
wiley +1 more source
Synthetic Ligands of Myeloid C‐Type Lectin Receptors
ChemBioChem, Volume 27, Issue 13, 14 July 2026.Binding of ligands to C‐type lectin receptors (CLRs) on myeloid cells can lead to an array of cellular responses. Exploitation of these receptors for therapeutic purposes requires high‐affinity ligands. This review surveys the diversity of synthetic ligands of myeloid CLRs in the context of binding, signaling, and downstream effects, as well as ...
James Suri, Bernd Lepenies
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The making of Samuel Beckett’s ‘Malone meurt’ / ‘Malone Dies’
, 2020 Originally published in French as Malone meurt in 1951 and later translated into English by the author himself, Malone Dies is the second novel of Samuel Beckett's Trilogy. The Making of Samuel Beckett's 'Malone Dies'/'Malone meurt' is a comprehensive reference guide to the history of the text.
Van Hulle, D, Verhulst, P
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Enantioselective Addition of Dialkyl Malonates to β-Arylethenesulfonyl Fluorides under High-Pressure Conditions. [PDF]
Org Lett, 2023 Kopyt M +3 more
europepmc +1 more source
Erratum: Further correction: Reductive annulations of arylidene malonates with unsaturated electrophiles using photoredox/Lewis acid cooperative catalysis. [PDF]
Chem SciBetori RC, McDonald BR, Scheidt KA.
europepmc +1 more source
Three Component Cascade Reaction of Cyclohexanones, Aryl Amines, and Benzoylmethylene Malonates: Cooperative Enamine-Brønsted Acid Approach to Tetrahydroindoles. [PDF]
ACS Omega, 2022 Cortes Vazquez J +7 more
europepmc +1 more source
Mechanistic Elucidation and Stereochemical Consequences of Alternative Binding of Alkenyl Substrates by Engineered Arylmalonate Decarboxylase. [PDF]
J Am Chem Socvan der Pol E +14 more
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