Gold‐Einzelatomkatalysatoren ermöglichen die selektive Shuttle‐Hydrochlorierung von Alkinen
Gold‐Einzelatomkatalysatoren auf Aktivkohle ermöglichen dank des Zusammenwirkens zwischen Au(I)‐Zentren und dem Träger die heterogene Shuttle‐Hydrochlorierung von terminalen Alkinen zu Vinylchloriden mit hoher Chemo‐ und Stereoselektivität. Das katalytische System vereint breite Substratverträglichkeit, vereinfachte Abtrennung und Wiederverwertbarkeit ...
Marc‐Eduard Usteri +8 more
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Record d'en Giuseppe Tavani (Roma, 21 de març 1924 - 22 de març 2019)
Veronica Orazi
doaj
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Gold Single‐Atom Catalysts Enable Selective Shuttle Hydrochlorination of Alkynes
Gold single‐atom catalysts on activated carbon enable heterogeneous shuttle hydrochlorination of terminal alkynes to vinyl chlorides with high chemo‐ and stereo‐selectivity thanks to cooperation between Au(I) sites and the support. The catalytic system combines broad substrate compatibility, simplified separation, and recoverability, paving the way for
Marc‐Eduard Usteri +8 more
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