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Mechanochemical Transformations of Biomass into Functional Materials
ChemSusChem, 2022AbstractBiomass is one of the promising alternatives to petroleum‐derived materials and plays a major role in our fight against climate change by providing renewable sources of chemicals and materials. Owing to its chemical and structural complexity, the transformation of biomass into value‐added products requires a profound understanding of its ...
Hajiali, Faezeh +5 more
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Synthesis of Biomaterials by Mechanochemical Transformation
Materials Science Forum, 2002Gema Gonzalez, Gonzalez Gema
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Kinetics of mechanochemical transformations
Physical Chemistry Chemical Physics, 2020To help understanding the mechanisms underlying mechanochemical transformations, we propose a kinetic model that relates macroscopic and microscopic scales while accounting for the statistical nature of the mechanical processing of powder.
Maria Carta +3 more
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Coupling of mechanical deformation and reaction in mechanochemical transformations
Physical Chemistry Chemical Physics, 2021Co-deformation and forced mixing contribute to the rate of chemical reaction between molecular solids subjected to mechanical processing.
Traversari G. +4 more
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The kinetics and energy balance of mechanochemical transformations
Physics of the Solid State, 2005AbstractFor Abstract see ChemInform Abstract in Full Text.
P. Yu. Butyagin, A. N. Streletskii
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Mechanochemical synthesis of alumina nanoparticles: Formation mechanism and phase transformation
Nanosized alumina powders were synthesized by mechanochemical treatment of stoichiometric mixture of anhydrous AlCl3 and CaO. X-ray powder diffraction (XRD), differential thermal and thermogravimetric analysis (DSC-TG), Fourier transform infrared ...
Jafar Javadpour +2 more
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Reaction Coordinates and Pathways of Mechanochemical Transformations
The Journal of Physical Chemistry B, 2015The notions of a reaction path and a reaction coordinate are central to chemistry as they provide low-dimensional descriptions of complex molecular processes. Here we discuss how to define, compute, and use the reaction paths for chemical transformations in molecules that are subjected to mechanical stress and thus driven toward regions of ...
Stanislav M, Avdoshenko +1 more
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Mechanochemical transformation of haematite to magnetite
Nanostructured Materials, 1995Abstract The transformation of α-Fe 2 O 3 to Fe 3 O 4 on wet-milling α-Fe 2 O 3 under low energy conditions in vacuum has been investigated by Mossbauer effect spectroscopy. The structural transformation is discrete with no evidence of interdissolution of the 2 phases.
S.J. Campbell +2 more
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Mechanochemical Radical Transformations in Organic Synthesis
Chemistry – A European JournalAbstract Organic synthesis has historically relied on solution‐phase, polar transformations to forge new bonds. However, this paradigm is evolving, propelled by the rapid evolution of radical chemistry. Additionally, organic synthesis is witnessing a simultaneous resurgence in mechanochemistry, the formation of new bonds in the solid ...
Sahra Sheikhaleslami, Jonathan Sperry
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Mechanochemically Induced Polymorphic Transformations of Sofosbuvir
Crystal Growth & Design, 2019Polymorphic studies of active pharmaceutical ingredients are of great importance for academic researchers as well as pharmaceutical industries, as each polymorph exhibits different physicochemical ...
Argyro Chatziadi +5 more
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