Impact of the Interfacial Molecular Structure Organization on the Charge Transfer State Formation and Exciton Delocalization in Merocyanine:PC61BM Blends [PDF]
The intermolecular charge transfer (CT) exciton in the merocyanine:[6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) system induced by the molecular geometry is investigated.
Budzinauskas K +8 more
core +1 more source
Ionogels dynamically and functionally couple ionic liquids with polymer networks, enabling multiscale programmable deformation and motion under electrical, magnetic, optical, thermal, humidity, and chemical stimuli. This article systematically elucidates the constituent components, structural design, and multiscale actuation mechanisms of ionogel ...
Dezhou Cao +5 more
wiley +1 more source
MXene‐Based Flexible Memory and Neuromorphic Devices
The unique two‐dimensional structure, excellent electrical conductivity, and diverse surface groups of MXenes have garnered significant attention. Coupled with their exceptional flexibility, MXene‐based devices hold immense potential for flexible memory and neuromorphic systems. This review comprehensively discusses the fundamentals of flexible devices,
Yan Li +13 more
wiley +1 more source
A groundbreaking dual‐donor crosslinking strategy was reported to significantly enhance the thermal stability, achieving remarkable EO coefficients (257–301 pm/V), glass transition temperatures (Tg) ranging from 107–187°C, and ultrahigh chromophore densities (3.73–4.26 × 10²⁰ molecules/cm³) with exceptional long‐term stability after 500 h at 85°C ...
Yu Zhang +7 more
wiley +1 more source
Thermally Bistable Stiff Stilbene Photoswitches and Polymer Applications
Thermally stable photoswitches offer new opportunities for controlling polymer structures and functions under nonequilibrium conditions. This Personal Account highlights stiff stilbene (SS) and sterically hindered stiff stilbene (HSS) photoswitches, which combine large structural changes with exceptional thermal bistability.
Keiichi Imato
wiley +1 more source
Electronic structure calculations and physicochemical experiments quantify the competitive liquid ion association and probe stabilisation effects for nitrobenzospiropyran in phosphonium-based ionic liquids. [PDF]
Liquid ion association in ionic liquids (ILs) has been examined using a comprehensive series of electronic structure calculations that measure the relative extents of ion association and probe stabilisation for the photochromic dye nitrobenzospiropyran ...
Byrne, Robert +3 more
core +1 more source
Light‐Modulated Humidity Sensing in Spiropyran Functionalized MoS2 Transistors
A hybrid material combining molybdenum disulfide (MoS2) and spiropyran for humidity and light responsiveness is developed. Ultraviolete (UV) irradiation tunes the wettability of MoS2 decorated by spiropyran, enhancing the humidity sensitivity. Water adsorption and photochromic doping significantly alter the optoelectronic properties of MoS2 flakes ...
Adrián Tamayo +4 more
wiley +1 more source
Synthesis and Optoelectronic Properties of Chemically Modified Bifluorenylidenes. [PDF]
The development of new light harvesting materials is a key issue for the progress of the research on organic & hybrid photovoltaics. Here, we report a new class of organic sensitizers based on the bi-fluorenylidene moiety as p-linker within the donor–p ...
Aragó, Juan +12 more
core +3 more sources
Photoacid‐Mediated Controllable Gelation in a Chemical Reaction Cycle
Visible‐light‐driven photoacid enables programmable hydrogelation in a dissipative CRN: irradiation intensity tunes sol‐gel timing and mechanics via in‐situ formaldehyde formation from hexamethylenetetramine. ABSTRACT We explore the use of a photoacid in a chemical reaction cycle, which allows for the controlled sol‐to‐gel transition of a saccharide ...
Alvaro Lopez‐Acosta +3 more
wiley +1 more source
Directed Evolution of a Bright Near-Infrared Fluorescent Rhodopsin Using a Synthetic Chromophore [PDF]
By engineering a microbial rhodopsin, Archaerhodopsin-3 (Arch), to bind a synthetic chromophore, merocyanine retinal, in place of the natural chromophore all-trans-retinal (ATR), we generated a protein with exceptionally bright and unprecedentedly red ...
Arnold, Frances H. +11 more
core +2 more sources

