Donor–acceptor Stenhouse aDdducts (DASAs) are known for their photoinduced tautomerization, which, when conjugated to block copolymers, can self‐assemble into tuneable polymersomes. These DASA‐polymersomes are being investigated for light‐controlled cargo release in biomedical applications.
Tristan N. Dell +10 more
wiley +1 more source
Large, Tunable, and Reversible pH Changes by Merocyanine Photoacids
Molecular photoswitches capable of generating precise pH changes will allow pH-dependent processes to be controlled remotely and noninvasively with light. We introduce a series of new merocyanine photoswitches, which deliver reversible bulk pH changes up
Andreásson, J +5 more
core +1 more source
Photo‐Modulated Proton Transport in Merocyanine Metastable‐State Photoacid Based Polymers
The covalent incorporation of merocyanine metastable‐state photoacid into soft polymers imparts conductivity to otherwise insulating matrices, allowing light‐triggered control of charge and structure, offering a new platform for photo‐responsive, ion‐conducting materials.
Gianni Pacella +5 more
wiley +1 more source
Stimuli-responsive materials as sensors and actuators in microfluidic devices [PDF]
The integration of stimuli-responsive materials into microfluidic systems can provide a means for external control over fluid flow and can reduce the overall complexity of microfluidic devices.
Diamond, Dermot +2 more
core
New generation solar cells: Concepts, trends and perspectives [PDF]
Organic, dye-sensitized and perovskite solar cell technologies have triggered widespread interest in recent years due to their very promising potential towards a high solar electricity future.
Ragoussi, Maria Eleni, Torres, Tomás
core +2 more sources
光照射によって生じたジメチン型メロシアニン(MD)の光異性体が,安定体にもどる速度過程を4種の誘導体について測定し,熱異性化速度定数(ka),活性化エネルギー(Ea)に対する複素環効果とプロトンの触媒作用の機構について調べた。kdは複素環の種類,とくに硫黄の導入数によって5ケタもの差となって現われた。溶媒の種類およびpHの変化によって島はいちじるしく変わるが,Eaはほとんど変わらないこと,Arrheniusの頻度因子はほとんど複素環効果を示さないことなどから,異性化の中間体としてプロトン化メロシアニンが重要な役割を果たしており,かつ,活性化エネルギーはプロトン移動過程の障壁ではなくプロトン付加体の内部回転の障壁を反映しているという結論を得た ...
Hitoshi FUNAKOSHI +5 more
openaire +2 more sources
Naphthopyran molecular switches and their emergent mechanochemical reactivity. [PDF]
McFadden ME +3 more
europepmc +1 more source
Petrosamine Revisited. Experimental and Computational Investigation of Solvatochromism, Tautomerism and Free Energy Landscapes of a Pyridoacridinium Quaternary Salt. [PDF]
Gartshore CJ, Wang X, Su Y, Molinski TF.
europepmc +1 more source
Recent Advances in N-Heterocyclic Small Molecules for Synthesis and Application in Direct Fluorescence Cell Imaging. [PDF]
Li Y, Liu T, Sun J.
europepmc +1 more source
Small Molecules with Spiro-Conjugated Cycles: Advances in Synthesis and Applications. [PDF]
Beloglazkina EK.
europepmc +1 more source

