Molecules, 2019 Crystalline polar metallocenes are potentially useful active materials as piezoelectrics, ferroelectrics, and multiferroics. Within density functional theory (DFT), we computed structural properties, energy differences for various phases, molecular ...
Haiwu Zhang, B.Yu. Yavorsky, R.E. Cohen
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Catalytic Undirected Meta‐Selective C–H Borylation of Metallocenes [PDF]
Advanced Science, 2023 Metallocenes are privileged backbones in the fields of synthetic chemistry, catalysis, polymer science, etc. Direct C–H functionalization is undoubtedly the simplest approach for tuning the properties of metallocenes.
Hao Zheng +6 more
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Synthesis and characterization of a formal 21-electron cobaltocene derivative [PDF]
Nature Communications, 2023 Metallocenes are highly versatile organometallic compounds. The versatility of the metallocenes stems from their ability to stabilize a wide range of formal electron counts.
Satoshi Takebayashi +8 more
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Alternative Metallocenes in Floating Catalyst-CVD: Synthesis of Novel Carbon Nanostructures [PDF]
Nanotechnology, Science and ApplicationsSandra Lepak-Kuc,1,2 Agnieszka Lekawa-Raus,2 Malgorzata Jakubowska,1,2 Krzysztof Koziol3 1Faculty of Mechanical and Industrial Engineering, Warsaw University of Technology, Warsaw, Poland; 2Centre for Advanced Materials and Technologies (CEZAMAT), Warsaw
Lepak-Kuc S +3 more
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Electrochemically driven regioselective C−H phosphorylation of group 8 metallocenes [PDF]
Nature Communications, 2022 Metallocene-based phosphines are compounds with potential use in catalysis. Here, the authors report the electrochemical regioselective functionalization of group 8 metallocenes with phosphine oxides; over 60 examples of phosphorylated (benzo)ferrocenes ...
Hao Zheng +8 more
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Anticancer Metallocenes and Metal Complexes of Transition Elements from Groups 4 to 7 [PDF]
MoleculesWith the progression in the field of bioinorganic chemistry, the role of transition metal complexes as the most widely used therapeutics is becoming a more and more attractive research area.
Irena Kostova
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Enantiomerically Pure ansa-η5-Complexes of Transition Metals as an Effective Tool for Chirality Transfer [PDF]
MoleculesChiral ansa-η5-complexes of transition metals have shown remarkable efficacy in organometallic synthesis and catalysis. Additionally, enantiomerically pure ansa-complexes hold promise for the development of novel chiral materials and pharmaceuticals. The
Pavel V. Kovyazin +2 more
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Trends in actinide electronic structure revealed from asymmetric, isostructural transuranic metallocenes [PDF]
Communications ChemistryThe study of actinide electronic structure and bonding within rigorously controlled environments is fundamental to advancing nuclear applications. Here, we report a new set of isostructural actinide organometallics; An(COTbig)2, (An = Th, U, Np, and Pu),
Cambell S. Conour +7 more
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Nickel(II)/BINOL-catalyzed enantioselective C–H activation via desymmetrization and kinetic resolution [PDF]
Nature CommunicationsThe field of nickel catalysis has witnessed remarkable growth in recent years. However, the use of nickel catalysts in enantioselective C–H activation remains a daunting challenge because of their variable oxidation states, intricate coordination ...
Qi-Jun Yao +3 more
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Thermally-induced nickelocene fragmentation and one-dimensional chain assembly on Au(111) [PDF]
Communications ChemistryThe ability to control molecular adsorption and transformation on surfaces is key to advancing nanoscale fabrication, catalysis, and quantum materials engineering. Transition-metal metallocenes, such as nickelocene (NiCp2), offer intriguing opportunities
Divya Jyoti +5 more
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