Results 91 to 100 of about 1,538 (201)

Isolation of Large Cage Erbium Metallofullerenes

, 2018
Erbium nitride clusters (i.e., Er3N) can be entrapped inside the cavity of fullerene cages. Of this family (e.g., Er3N@C2n) of compounds, Er3N@C80 is the dominant species. However, there is a paucity of literature on these clusters with larger cages (e.g.
Davison, Cody
core   +1 more source

Gd@C82 metallofullerenes for neutron capture therapy—fullerene solubilization by poly(ethylene glycol)-block-poly(2-(N, N-diethylamino)ethyl methacrylate) and resultant efficacy in vitro

Science and Technology of Advanced Materials, 2011
Poly(ethylene glycol)-block-poly(2-(N,N-diethylamino)ethyl methacrylate) (PEG-b-PAMA) was found to solubilize fullerenes such as C60, and this technique was applied to metallofullerenes.
Yukichi Horiguchi, Shinpei Kudo and Yukio Nagasaki
doaj  

Improved Production and Separation Processes for Gadolinium Metallofullerenes

, 2016
A comprehensive scheme for processing all arc-produced gadolinium monometallofullerenes into separate quantified fractions is presented. As generated by the carbon arc process, endohedral metallofullerenes are entrained in a complex mixture of more ...
James W. Raebiger (2377276), Robert D. Bolskar (2377267)   +1 more
core   +1 more source

Process Parameter Optimisation for Endohedral Metallofullerene Synthesis via the Arc-Discharge Method

Inorganics
Fullerenes have a unique structure, capable of both encapsulating other molecules and reacting with those on the exterior surface. Fullerene derivatives have also been found to have enormous potential to address the challenges of the renewable energy ...
Sapna Sinha, Karifa Sanfo, Panagiotis Dallas, Sujay Kumar, Kyriakos Porfyrakis   +4 more
doaj   +1 more source

Electrically controlled nonvolatile switching of single-atom magnetism in a Dy@C84 single-molecule transistor

Nature Communications
Single-atom magnetism switching is a key technique towards the ultimate data storage density of computer hard disks and has been conceptually realized by leveraging the spin bistability of a magnetic atom under a scanning tunnelling microscope.
Feng Wang, Wangqiang Shen, Yuan Shui, Jun Chen, Huaiqiang Wang, Rui Wang, Yuyuan Qin, Xuefeng Wang, Jianguo Wan, Minhao Zhang, Xing Lu, Tao Yang, Fengqi Song   +12 more
doaj   +1 more source

Different Extraction Behaviors between Divalent and Trivalent Endohedral Metallofullerenes

, 2016
On the basis of high-yield preparation, arc-produced soot containing endohedral Y, La, Nd, Sm, Gd, Tb, Yb, Ca, and Ba fullerenes are successively extracted with carbon disulfide, N,N-dimethylformamide, pyridine, and aniline.
Xihuang Zhou (2718508), Zhennan Gu (193159), Zujin Shi (1607182), Yongfu Lian (1979206)   +3 more
core   +1 more source

Geometries, Electronic Structures, Bonding Properties, and Stability Strategy of Endohedral Metallofullerenes TM@C₂₈ (TM = Sc⁻, Y⁻, La⁻, Ti, Zr, Hf, V⁺, Nb⁺, Ta⁺)

Inorganics
We performed quantum chemical calculations on the geometries, electronic structures, bonding properties, and stability strategy of endohedral metallofullerenes TM@C28 (TM = Sc−, Y−, La−, Ti, Zr, Hf, V+, Nb+, Ta+). Our calculations revealed that there are
Dong Liu, Yuan Shui, Tao Yang
doaj   +1 more source

Water-soluble endohedral metallofullerenes: new horizons for biomedical applications. [PDF]

Chem Commun (Camb), 2023
Kopcha WP, Biswas R, Sun Y, Chueng SD, Dorn HC, Zhang J.   +5 more
europepmc   +1 more source

Endohedral Metallofullerenes Today: More and More Versatile Ships in Multiform Bottles-Electrochemistry of X-Ray Characterized MonometallofullerenesAdvances in Organometallic Chemistry and Catalysis

, 2013
Endohedral Metallofullerenes Today: More and More Versatile Ships in Multiform Bottles—Electrochemistry of X-Ray Characterized ...
ZANELLO, PIERO, FABRIZI DE BIANI, FABRIZIA, Fabrizia Fabrizi de Biani, Piero Zanello   +3 more
core   +1 more source

Endohedral metallofullerenes and method for making the same

, 1999
A family of trimetallic nitride endohedral metallofullerenes and their preparation are described. The trimetallic nitride endohedral metallofullerenes have the general formula A.sub.3-n X.sub.n @C.sub.m where n ranges from 0 to 3, A and X may be ...

core