Results 71 to 80 of about 1,538 (201)
Endohedral metallofullerene molecular nanomagnets
This review summarizes the significant advances in endohedral metallofullerene-based molecular nanomagnets, with a particular emphasis on their unique structures and intriguing magnetic properties arising from such structural peculiarity.
Ziqi Hu, Shangfeng Yang
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Structures of Endohedral Metallofullerenes
The structures of many typical endohedral metallofullerenes have been reported by the powder X-ray analysis. For example, the report of the trimetallofullerene Sc3C82has shown that the endohedral structure is Sc3@C82, this being widely accepted. However, the recent13C NMR spectroscopy and X-ray single crystal analysis have revealed that the structure ...
AKASAKA, Takeshi, NAGASE, Shigeru
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A simple method for the selective enrichment of endohedral metallofullerenes
The concentration of a polar solvent DMF extract was found to be very effective for the selective enrichment of endohedral metallofullerenes against empty fullerenes.
Huang, Houjin +4 more
core
Exohedral Diels‐Alder Reactivity of Endohedral Metallofullerene C36
The preferential position of 3d metal atoms inside the C36 cage and their effect on exohedral Diels‐Alder reactivity is reported in comparison with the empty C360 and C362− cages. Among all [5‐5], [6‐5] and [6 6] C−C bonds the [5‐5] bond is the most reactive bond in both the empty C36 and metallofullerene M@C36.
Athul Santha Bhaskaran +4 more
wiley +1 more source
The Isolation of Endohedral Metallofullerenes with Octadecylsilica Columns
Octadecylsilica (ODS) columns have been used for the first time in the purification of endohedral metallofullerenes. In the absence of any pi-pi interaction between the analytes and the stationary phase, the separation selectivity of fullerenes and ...
Tso, T.S.C. +7 more
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Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes
The [4 + 2] cycloaddition of o-quinodimethanes, generated in situ from the sultine 4,5-benzo-3,6-dihydro-1,2-oxathiin 2-oxide and its derivative, to La metal-encapsulated fullerenes, La2@C80 or La@C82, afforded the novel derivatives of endohedral ...
Yuta Takano +4 more
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The Supramolecular Chemistry of Cycloparaphenylenes and Their Analogs
Cycloparaphenylenes (CPPs) and their analogs have recently attracted much attention due to their aesthetical structures and optoelectronic properties with radial π-conjugation systems.
Dapeng Lu +5 more
doaj +1 more source
Copper Chloride as a Selective Precipitation Agent for Purifying Endohedral Metallofullerenes [PDF]
In our lab we are pursuing separation strategies for isolating new molecules discovered in our lab. Our new molecules consist of clusters consisting of metals, nitrogen, and/or oxygen entrapped within fullerene cages.
Rottinger, Khristina
core
Background The hallmark of atherosclerosis is the accumulation of plaque in vessel walls. This process is initiated when monocytic cells differentiate into macrophage foam cells under conditions with high levels of atherogenic lipoproteins.
Dellinger Anthony +7 more
doaj +1 more source
A Reinvestigation of Coalescence Reactions of Fullerenes
Gas-phase studies of fullerenes and metallofullerenes, though less well explored compared to condensed-phase research in recent years, offer critical insights into the mechanisms governing their formation and behavior.
Shumei Yang +5 more
doaj +1 more source

