Results 91 to 100 of about 9,317 (210)
Catalytic Amyloids: Turning Fibrils Into Biocatalysts
Amyloids, traditionally associated with diseases, have emerged as versatile catalytic scaffolds. From natural amyloid sequences to bioinspired and de novo designs, we highlight strategies to construct catalytic active sites and anchor enzymes onto fibrils, creating versatile nanomaterials with tunable activities. ABSTRACT Amyloids have been regarded as
Alessandra Esposito +3 more
wiley +1 more source
Layered materials are a very interesting class of compounds obtained by stacking of two-dimensional layers along the basal axis. A remarkable property of these materials is their capacity to interact with a variety of chemical species, irrespective of ...
Shirley Nakagaki +4 more
doaj +1 more source
5,15-Diaryl-beta-substituted-porphyrinato-manganese(III) chlorides as probes for structure-activity relationships in porphyrin-based epoxidation catalysts [PDF]
Manganese complexes of 5,15-diaryl-beta-substituted-porphyrins were prepared and their behaviour as oxidation catalysts was studied. The role of the pyrrolic and meso-substituents on the activity and selectivity of these catalysts was studied to reveal ...
Gonsalves, António M. d'A. Rocha +1 more
core +1 more source
Cu‐based catalysts as a cornerstone in advancing sustainable energy technologies are fully reviewed in this manuscript, highlighting their potential in photo‐ and electrocatalysis. It includes metallic copper, copper oxides, copper sulfides, copper halide perovskites, copper‐based metal–organic frameworks (MOFs), and covalent organic frameworks (COFs),
Jéssica C. de Almeida +16 more
wiley +1 more source
Biomimetic catalytic conversion of carbohydrates to low-molecular weight (LWM) organic acids was investigated in the presence of sulfonated metalloporphyrins (MTSPP, M = Fe, Mn, Co, Cu), with dioxygen as the oxidant.
Qiang Liu +5 more
doaj +1 more source
Deep-red electrophosphorescence from a platinum(II)–porphyrin complex copolymerised with polyfluorene for efficient energy transfer and triplet harvesting [PDF]
A series of polyfluorene-based polymers with a range of weight percentages (w/w) of a platinum(II)-containing porphyrin, 5,15-dimesityl-10,20-diphenylporphyrinato platinum(II) (MPP(Pt)), were synthesised and incorporated into organic light-emitting ...
Bronstein, H +5 more
core +2 more sources
Organic and Metallacages for Chemical Sensing: Progress in Water‐Compatible Systems
Supramolecular cages function as three‐dimensional receptors for selective molecular recognition and sensing, and this review outlines design principles for water‐stable architectures, key analyte‐ and medium‐dependent challenges, recent water‐compatible examples (including polymer‐integrated systems), and future opportunities for cage‐based ...
Rabia Zahid +4 more
wiley +1 more source
Chemically Engineering Magnetic Anisotropy of 2D Metalloporphyrin
Continuous miniaturization of magnetic units in spintronics devices inspires efforts to search for novel 2D magnetic materials with giant magnetic anisotropy energy (MAE).
Peng Wang, Xue Jiang, Jun Hu, Jijun Zhao
doaj +1 more source
In recent years, scientific advancements have constantly increased at a significant rate in the field of biomedical science. Keeping this in view, the application of porphyrins and metalloporphyrins in the field of biomedical science is gaining ...
Muhammad Imran +4 more
doaj +1 more source
Connecting [4Fe–4S] Clusters and Hemes – Towards Modeling the Active Site of Sulfite Reductase [PDF]
In this paper, we present a new design for biologically inspired models for the active site of assimilatory sulfite and nitrite reductases (aSIR and aNIR), which consists of a siroheme that is directly linked to a [4Fe–4S] cubane cluster.
Lu, Connie C., Meyer, Karsten
core +1 more source

