Results 81 to 90 of about 11,207 (210)
The Hemoprotein Hhy1 Promotes Heme‐Dependent Catalase Activity of Ctt1
A Schizosaccharomyces pombe strain deficient in heme (hem1Δ) and siderophore (Fc) biosynthesis, as well as high‐affinity iron (Fe) uptake (blue), was used to uncover the hemoprotein Hhy1 that promotes the heme‐dependent activity of the catalase Ctt1. In contrast, hhy1Δ cells exhibit reduced Ctt1 activity and increased sensitivity to oxidative stress ...
Tobias Vahsen +3 more
wiley +1 more source
Recent Advances in Homogeneous Metal-Catalyzed Aerobic C–H Oxidation of Benzylic Compounds [PDF]
Csp(3)-H oxidation of benzylic methylene compounds is an established strategy for the synthesis of aromatic ketones, esters, and amides. The need for more sustainable oxidizers has encouraged researchers to explore the use of molecular oxygen.
Domínguez Pérez, Pilar Esther +3 more
core +3 more sources
Resonance Raman Interrogation of the Consequences of Heme Rotational Disorder in Myoglobin and its Ligated Derivatives [PDF]
Resonance Raman spectroscopy is employed to characterize heme site structural changes arising from conformational heterogeneity in deoxyMb and ligated derivatives, i.e., the ferrous CO (MbCO) and ferric cyanide (MbCN) complexes.
Kincaid, James R. +2 more
core +3 more sources
Cardanol, a well known hazardous byproduct of the cashew industry, has been used as starting material for the synthesis of useful differently substituted “cardanol-based” porphyrins and their zinc(II), copper(II), cobalt(II) and Fe(III) complexes.
Giuseppe Mele +5 more
doaj +1 more source
Hydrocarbon oxidation catalyzed by iron and manganese porphyrins anchored on aminofunctionalized supports [PDF]
The second-generation metalloporphyrins (MePs) [5,10,15,20-tetrakis(pentafluorophenyl)porphyrin iron(III)] chloride, FeP, and [5,10,15,20-tetrakis(pentafluorophenyl)porphyrin manganese(III)] chloride, MnP, were covalently attached to aminofunctionalized ...
ASSIS, Marilda D. +3 more
core +1 more source
Die Implementierung von Kronenethern in den Liganden von Kobaltporphyrinen wirkt sich in mehrfacher Hinsicht positiv auf die elektrochemische CO2‐Reduktion aus: 1. Das Reduktionspotenzial wird in Gegenwart von K+ gesenkt; 2. die CO‐Erzeugung in Zero‐Gap‐Elektrolyseuren wird gesteigert und 3.
Wiebke Wiesner +7 more
wiley +1 more source
Ditopic binding of various dinitrogen compounds to three bisporphyrin molecular tweezers with spacers of varying conformational rigidity, incorporating the planar enediyne (1), the helical stiff stilbene (2), or the semi-rigid glycoluril motif fused to ...
Magnus Blom +7 more
doaj +1 more source
MODIFICATION OF WATER POLYMER COMPOSITIONS FOR ELECTRODEPOSITION BY METALLOPORPHYRINS
It is known that coatings produced by electrodeposition, cured at high temperatures (180ºC and above).The aim of this study is reducing the energy intensity of production of polymer coatings, improving physical, mechanical properties of the polymer ...
G. N. Bespalova +5 more
doaj +1 more source
Catalytic Amyloids: Turning Fibrils Into Biocatalysts
Amyloids, traditionally associated with diseases, have emerged as versatile catalytic scaffolds. From natural amyloid sequences to bioinspired and de novo designs, we highlight strategies to construct catalytic active sites and anchor enzymes onto fibrils, creating versatile nanomaterials with tunable activities. ABSTRACT Amyloids have been regarded as
Alessandra Esposito +3 more
wiley +1 more source
Mass spectrometry of metalloporhyrins. 1. Mass spectra of octaethylporphines cobalt, nickel, copper
Mass spectra of octaethylporphyrines of cobalt, nickel, copper with electron ionization were obtained. Molecular ions with isotope peaks and the peaks formed by separation hydrogen atoms from porhyrins core have maximum intensity.
A. A. Perov +3 more
doaj

