Results 181 to 190 of about 34,844 (261)

High-spin surface Fe^IV = O synthesis with molecular oxygen and pyrite for selective methane oxidation. [PDF]

Nat Commun
Ling C, Li M, Li H, Liu X, Guo F, Liu Y, Zhang R, Zhao J, Zhang L.   +8 more
europepmc   +1 more source

A New Spin on Photocatalysis: Vortex Fluidic‐Driven Photooxidations Enabled by Solution‐Processable Microporous Polymers

Chemistry – A European Journal, EarlyView.
Newly developed polymers with intrinsic microporosity (PIMs) were combined with benzo[c][1,2,5]thiadiazole (BTZ) to be used as visible light photocatalytic coatings on the Vortex Fluidic Device (VFD). The VFD's rapid rotation and continuous flow capabilities enhanced singlet oxygen and superoxide radical reactions, achieving a dramatic eightfold ...
Leonardo Amicosante, Fiona R. Gordon, Dominic Taylor, Neil B. McKeown, Daniel M. Jubb, Stuart R. Kennedy, Marc A. Little, Filipe Vilela, Colin L. Raston, Scott J. Dalgarno   +9 more
wiley   +1 more source

Why Testing Protocols Matter in Electrochemical Methane Oxidation: Insights from IrO _<i>x</i> in Acid. [PDF]

ACS Energy Lett
Arminio-Ravelo JA, Favero S, Escudero-Escribano M.   +2 more
europepmc   +1 more source

Controlled Formation and Unusual Reactivity of Cyanohexatriyne (HC7N), a Synthetically Challenging Interstellar Cyanopolyyne

Chemistry – A European Journal, EarlyView.
First controlled formation of cyanohexatriyne (HC7N) is achieved using a cobalt–alkyne masking strategy that overcomes the intrinsic instability of nitrile‐substituted polyynes. The approach enables spectroscopic validation of HC7N and reveals its pronounced electrophilicity through a selective conjugate addition with diethylamine.
Léa Lefrançois, Mano Cremer, Thierry Roisnel, Jean‐Claude Guillemin, Yann Trolez   +4 more
wiley   +1 more source

Higher temperature sensitivity of forest soil methane oxidation in colder climates. [PDF]

Nat Commun
Jiang B, Chen H, Wei Z, Zhang J, Guo M, Yang T, Zhou X.   +6 more
europepmc   +1 more source

The Rich Chemistry of Ionized Methanol With Sulfur Dioxide: Pathways to Prebiotic and Elusive Species in Earth's Atmosphere and Space

Chemistry – A European Journal, EarlyView.
The reaction between the methanol radical cation and sulfur dioxide is remarkably fast and forms several ionic and neutral products (HOSOH+, CH2OSO+, CH2OH+, CH2O, H2O, HSO2). The chemistry goes beyond simple proton or hydrogen transfer, revealing a close interaction between the two species, relevant to atmospheric and astrochemical environments where ...
Mauro Satta, Daniele Catone, Mattea Carmen Castrovilli, Antonella Cartoni   +3 more
wiley   +1 more source

Orchestrating Multi-Ångstrom Spaced Cu─Ni Dual-Atom Pair for Synergistic C─H Activation in Direct Methane Oxidation to Methanol. [PDF]

Adv Sci (Weinh)
Jin J, Li W, Wang L, Zhang L, Zhang X.
europepmc   +1 more source

Ni2‐Imido Bispincer Platforms: Cooperative Reactivity Enabled Through Substrate Addition Across a Ni2N Unit

Chemistry – A European Journal, EarlyView.
Ni2 bispincer complexes with an embedded central imido anchor are presented. The bispincer complexes leverage the high basicity of imido ligands to facilitate 1,2 addition of weak B─H and Si─H bonds, resulting in hydrido–amido complexes and resultingly a contortion of a Ni─Ni sigma bond to form an S = 1 species. The 1,2 addition is proposed to serve as
David de los Santos, Kritika Gour, Manar M. Shoshani   +2 more
wiley   +1 more source

Climate-induced shifts in sulfate dynamics regulate anaerobic methane oxidation in a coastal wetland. [PDF]

Sci Adv
Lee J, Yang Y, Kang H, Noyce GL, Megonigal JP.   +4 more
europepmc   +1 more source

Unbiased Reaction Network Exploration of C–C Coupling in Methane Dehydroaromatization Over Mo‐ZSM‐5

Chemistry – A European Journal, EarlyView.
Automated reaction route mapping reveals distinct methane coupling pathways over mono‐ and dinuclear Mo carbide species in ZSM‐5. Mononuclear [MoC]2+ selectively forms desorbable C2H4, whereas dinuclear [Mo2C2]2+ promotes strongly adsorbed C3/C4 intermediates linked to coke formation.
Shunsaku Yasumura, Masaru Ogura
wiley   +1 more source