Structural diversity in alkali metal and alkali metal magnesiate chemistry of the bulky 2,6-diisopropyl-N-(trimethylsilyl)anilino ligand [PDF]
, 2016 Bulky amido ligands are precious in s-block chemistry since they can implant complementary strong basic and weak nucleophilic properties within compounds. Recent work has shown the pivotal importance of the base structure with enhancement of basicity and
Anctil +97 more
core +1 more source
Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†
Chinese Journal of Chemistry, EarlyView.A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley +1 more source
New class of thermosetting plastics has improved strength, thermal and chemical stability [PDF]
, 1967 New class of thermosetting plastics has high hydrocarbon content, high stiffness, thermal stability, humidity resistance, and workability in the precured state.
Burns, E. A. +2 more
core +1 more source
Volatile hydrocarbons inhibit methanogenic crude oil degradation [PDF]
, 2014 Methanogenic degradation of crude oil in subsurface sediments occurs slowly, but without the need for exogenous electron acceptors, is sustained for long periods and has enormous economic and environmental consequences.
Angela eSherry +6 more
core +3 more sources
A walk in the park—Identifying healthy greenspaces using scents
PLANTS, PEOPLE, PLANET, EarlyView.As urbanisation accelerates globally, access to nature is increasingly recognised as vital for public health and wellbeing. We captured and analysed plant‐emitted airborne ‘scent signatures’ across Oxford's urban greenspaces to assess their potential health relevance.
William T. Kay +6 more
wiley +1 more source
β-Cyclodextrins grafted with chiral amino acids: A promising supramolecular stabilizer of nanoparticles for asymmetric hydrogenation? [PDF]
, 2013 International audienceWater-soluble ruthenium nanoparticles stabilized by randomly methylated β-cyclodextrins (RaMeCDs) grafted with chiral amino-acid moieties like l-alanine (Ala) and l-leucine (Leu) were prepared in aqueous solution by two approaches: (
Chau, Nguyet Trang Thanh +8 more
core +3 more sources
CHIMIA, 1990 A specifically designed metal vapor synthesis apparatus makes possible the semi-quantitative assessment of the reactivities for the elements of the first transition series toward p-bromotoluene kept in a ?118°C solution of methylcyclohexane.
Jean-Claude Négrel +2 more
doaj +5 more sources
Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations [PDF]
, 2012 The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described. The method employs a readily accessible catalyst (NiBr[subscript 2]·diglyme/4,4′-di-tert-butyl-2,2′-bipyridine, both commercially available) and represents the ...
de Meijere A. +32 more
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Open Notebook Science Challenge: Solubilities of Organic Compounds in Organic Solvents [PDF]
, 2010 This book contains the results of the Open Notebook Science Solubility Challenge. All experimental measurements are provided with a link to either the laboratory notebook page where the experiment was carried out or to a literature reference.
Andrew Lang +17 more
core +6 more sources
ChemSystemsChem, Volume 8, Issue 3, May 2026.This study focuses on the supramolecular self‐assembly of a newly developed family of compounds featuring s‐tetrazine. In particular, we highlight structure‐property relations and how gelation and mesogenic properties can be directed as a consequence of different side chains introduced in the system.
Lucrezia Trevisan +9 more
wiley +1 more source