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Rheology of giant micelles [PDF]
Giant micelles are elongated, polymer-like objects created by the self-assembly of amphiphilic molecules (such as detergents) in solution. Giant micelles are typically flexible, and can become highly entangled even at modest concentrations. The resulting viscoelastic solutions show fascinating flow behaviour (rheology) which we address theoretically in
Cates, M. E., Fielding, S. M.
openaire +5 more sources
The micellar and surface behaviors of decylammonium chloride (DACl) in presence of L-alanine hydrochloride decylester (L-ADE) and L-alanine hydrochloride dodecylester (L-ADDE) at various mole fractions were investigated by conductivity and surface ...
Elif Berna Olutas
doaj +1 more source
The surface tension of aqueous solutions of Triton X-165 with rhamnolipid or surfactin mixtures was measured. The obtained results were applied for the determination of the concentration and composition of the Triton X-165 and biosurfactants mixture at ...
Edyta Rekiel+3 more
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The micellization and surface activity properties of long-chain pyridinium ionic liquids n-alkyl-3-methylpyridinium bromide ([Cnmpy][Br], n: the carbon numbers of hydrophobic tails, n = 12, 14, 16) in aqueous solution were systematically investigated ...
Dongxu Fu+9 more
semanticscholar +1 more source
Recent Advances in Heterogeneous Frustrated Lewis Pair: Synthesis, Characterization, and Catalysis
This review provides a concise analysis of heterogeneous frustrated Lewis pair (FLP) chemistry, focusing on their synthesis, characterization, and application in small‐molecule activation. It highlights current challenges in developing solid FLP systems and explores promising advancements through emerging technologies, offering critical insights into ...
Jiasi Li+2 more
wiley +1 more source
Ultrathin Mesoporous Metal‐Organic Framework Nanosheets
A bottom‐up interface‐directed co‐assembly strategy enables the synthesis of ultrathin 2D mesoporous UiO‐66(Ce) nanosheets with tunable thickness and uniform mesopores. The enhanced mass transport and accessible active sites significantly improve performance, highlighting the synergistic effects of 2D morphology and mesopores in metal‐organic ...
Yingji Zhao+12 more
wiley +1 more source
In Situ Measurements of Polymer Micellization Kinetics with Millisecond Temporal Resolution.
Utilizing synchrotron small-angle X-ray scattering (SAXS) integrated with a microfluidic device, micellization kinetics of a diblock co-polymer, poly(ethylene glycol)-b-poly(caprolactone) (PEG-b-PCL) was measured in situ with millisecond temporal and ...
Joseph Kalkowski+8 more
semanticscholar +1 more source
Due to the increasing practical use of mixtures of flavonoids with nonionic surfactants the presented studies were based on the measurements of surface tension and conductivity of aqueous solution of the quercetin (Q) and rutin (Ru) in the mixtures with ...
Anna Taraba+3 more
doaj +1 more source
This study develops an amphiphilic copolymer nanocarrier (P(His‐r‐Sty)‐b‐PDMAA) for aqueous hemin catalysis, enabling efficient styrene cyclopropanation (94.4% yield, 0.3 mol% hemin) with excellent recyclability (>90% activity after 4 cycles), overcoming solubility and microenvironment challenges.
Lulu Chen+4 more
wiley +1 more source
Colloid-chemical properties of surfactant–nitric acid–water systems
The behavior of the surfactants Tween 80, SaS and alkyl betaine in aqueous and nitric acid environments as promising additives for nitrate leaching of hard-to-process ore concentrates of non-ferrous metals was studied.
Lev Danilin+3 more
doaj +1 more source