Results 101 to 110 of about 12,962 (261)

A New Paradigm for Understanding the Rheology and Processability of Poly(p‐Phenylene Terephthalamide) Liquid‐Crystalline Solutions

open access: yesJournal of Applied Polymer Science, EarlyView.
Kevlar is traditionally modeled as a rigid‐rod polymer, yet rheological behavior deviates from this assumption. The review introduces a novel “twist‐tie” entanglement theory for aramid polymer chains in the nematic liquid crystal state, providing a molecular explanation for deviations from rigid‐rod models. Understanding twist‐tie entanglement dynamics
Emma Egli   +3 more
wiley   +1 more source

Evaluation of the Efficiency of a Biobased Reactive Plasticizer on the Morphology and Properties of Sustainable Flexible Films Based on Poly(Lactic Acid) (PLA) Produced by Blown Film Extrusion

open access: yesJournal of Applied Polymer Science, EarlyView.
A comparative investigation of two epoxy additives derived from cardanol (NC513 and NC514s) for production of films based on poly (lactic acid) (PLA), acetyl tributyl citrate (ATBC), and poly (butylene adipate‐co‐terephthalate) (PBAT) clarified their distinct roles, with NC513 mainly acting as a plasticizer, reducing viscosity and enhancing ductility ...
Norma Mallegni   +3 more
wiley   +1 more source

Additives Enhancing Biodegradability in Plastics and Potential Implications for Textiles: A Mechanistic Review

open access: yesJournal of Applied Polymer Science, EarlyView.
Mechanistic insights from additive‐assisted plastic degradation guide the design of environmentally adaptive textile fibers. Functional additives enhance oxidative, hydrolytic, enzymatic, and microbial degradation pathways. Translating these strategies requires control of fiber architecture, additive distribution, and environmental interactions ...
Julia Cunniffe   +2 more
wiley   +1 more source

From brush conformation to 3D Supraparticles: Programmable self‐assembly of polymer‐grafted nanoparticles in emulsion confinement

open access: yesBulletin of the Korean Chemical Society, EarlyView.
This review highlights how the conformational adaptability of polymer‐grafted nanoparticles drives their programmable self‐assembly within 3D emulsion droplets. By coupling brush thermodynamics with soft confinement, these dynamic building blocks form hierarchical supraparticles tailored for advanced plasmonics, compartmentalized catalysis, and stimuli‐
Hongseok Yun
wiley   +1 more source

Screening of Polymers for Oral Ritonavir Amorphous Solid Dispersions by Film Casting

open access: yesPharmaceutics
Background/Objectives: Drug–polymer interactions and miscibility promote the formation and performance of amorphous solid dispersions (ASDs) of poorly soluble drugs for improved oral bioavailability. The objective of this study was to employ drug–polymer
Ayse Nur Oktay, James E. Polli
doaj   +1 more source

Maize Kernel Composition and Morphology Influences Pericarp Retention During Nixtamalization

open access: yesCereal Chemistry, EarlyView.
Abstract Background and Objectives Pericarp retention during nixtamalization directly influences masa quality, affecting texture, machinability, and nutritional content of staple foods such as tortillas and chips. Despite its industrial relevance, the underlying kernel traits that govern pericarp retention remain poorly characterized.
Michael J. Burns   +4 more
wiley   +1 more source

High‐Performance Solid‐State Lithium Batteries via Dipole‐Matching: Enabling Compact Polymer Microstructure and Stable Interfaces

open access: yesCarbon Energy, EarlyView.
A dipole–matching strategy is proposed to engineer PVDF‐HFP solid polymer electrolytes by incorporating 3,5–bis(trifluoromethyl)benzoic acid. Dipole interactions regulate polymer nucleation and phase alignment, forming compact microstructures, while controlled FSI– decomposition induces a LiF–rich interphase, enabling fast Li+ transport, uniform ...
Ya Song   +11 more
wiley   +1 more source

Intrinsically Ultrahigh‐Rate Charging Capability of Conversion Reaction Cathodes and Its Origin: A Mechanism Study on FeS2

open access: yesCarbon Energy, EarlyView.
Origin of the ultrahigh‐rate charge capability of FeS2: FeS2 demonstrates exceptional high‐rate charging capability, delivering 92% capacity retention at 10 C and maintaining as much as 60% capacity retention even at 30 C. This originates from an ultrahigh apparent diffusion coefficient involving both Li+ and Fe2+.
Zhen Yu   +13 more
wiley   +1 more source

Infinite Functional Versatility, Formidable Limits: Evaluating Gallium‐Based Liquid Metals in Rechargeable Batteries

open access: yesCarbon Energy, EarlyView.
Beyond the hype surrounding the self‐healing properties of gallium‐based liquid metals (Ga‐LMs), this perspective critically examines their functional roles in metal‐ion batteries, highlighting both their underlying merits and the often‐overlooked challenges, including non‐representative design and testing configurations, performance overestimations ...
Turly P. P. Sumanasekara   +7 more
wiley   +1 more source

Noise‐Blocking Interfacial Lamination of Small‐Molecule Acceptors for Enhanced Signal Clarity in Organic Photodetectors

open access: yesCarbon Energy, EarlyView.
The structural design strategy employing the Y6‐BO interfacial lamination suppresses dark current by limiting solvent‐induced interfacial damage through the formation of uniformly arranged interfaces while optimizing charge transport to achieve superior detectivity.
Jihyun Lim   +4 more
wiley   +1 more source

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