Results 221 to 230 of about 3,301,387 (267)
MitoClipSplice: a machine learning framework for resolving mitochondrial RNA cleavage sites from strand-specific RNA-seq soft-clips. [PDF]
Yuan Q +10 more
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Synthesis and Supramolecular Properties of Molecular Clips with Anthracene Sidewalls
Chemistry - A European Journal, 2005AbstractNovel molecular clips with anthracene sidewalls (1 a–c) were synthesized; they form stable host–guest complexes with a variety of electron‐deficient aromatic and quinoid molecules. According to single‐crystal structure analyses of clip 1 c and 1,2,4,5‐tetracyanobenzene (TCNB) complex 14@1 b, the clips’ anthracene sidewalls have to be compressed
Alberto Juris
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Synthesis and supramolecular structures of molecular clips
Tetrahedron, 2001The syntheses of the novel dimethylene-bridged clips I (n = 0, R = H, OAc, OH, OMe, OSO2CF3; n = 1, R = OAc) are reported. They selectively bind electron-deficient neutral and cationic arom. substrates comparable to tetramethylene-bridged tweezers. The geometry of the noncovalently bound complexes with I (n = 0; R = OAc, OH, OMe) as receptors, derived ...
Klärner, Frank-Gerrit +3 more
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Chiral Molecular Clips Control Orthogonal Crystalline Organization
Organic Letters, 2007Chiral molecular clips constitute a robust system for crystal engineering studies and undergo several levels of orthogonal organization including heterochiral dimerization, H-bond or metal-ligand mediated tape formation, and longitudinal packing of the tapes.
An-Xin Wu, Nengfang She, Lyle Isaacs
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Assembling Molecular Clips To Build π‐Stacks
Chemistry – A European Journal, 2023AbstractNature utilizes an intimate stacking of aromatic motifs to construct functional structures, as demonstrated in protein folding and polynucleotide assembly. However, organized π‐stacks of artificial molecules are difficult to build, primarily due to the weak, non‐directional, and context‐sensitive nature of van der Waals forces.
Hyun Lee, Dongwhan Lee
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The Journal of Organic Chemistry, 2008
We report the synthesis and characterization of 12 C-shaped methylene-bridged glycoluril dimers (1-12) bearing H-bonding groups on their aromatic rings. Compounds 1, 2, (+/-)-4a, (+/-)-5, (+/-)-7, and 8 form tightly associated homodimers in CDCl3, due to the combined driving force of pi-pi and H-bonding interactions. Compounds 2, (+/-)-5, and 8, having
Soumyadip, Ghosh +4 more
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We report the synthesis and characterization of 12 C-shaped methylene-bridged glycoluril dimers (1-12) bearing H-bonding groups on their aromatic rings. Compounds 1, 2, (+/-)-4a, (+/-)-5, (+/-)-7, and 8 form tightly associated homodimers in CDCl3, due to the combined driving force of pi-pi and H-bonding interactions. Compounds 2, (+/-)-5, and 8, having
Soumyadip, Ghosh +4 more
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Alligator clips to molecular dimensions
Journal of Physics: Condensed Matter, 2008Techniques for fabricating nanospaced electrodes suitable for studying electron tunneling through metal-molecule-metal junctions are described. In one approach, top contacts are deposited/placed on a self-assembled monolayer or Langmuir-Blodgett film resting on a conducting substrate, the bottom contact.
Nicholas, Prokopuk, Kyung-Ah, Son
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Clip[5]arenes: A new family of molecular clips
Tetrahedron Letters, 2018Abstract Here we report the design and syntheses of two new triptycene-based rigid acyclic C-shaped hosts, clip[5]arenes C[5]OH and C[5]ME, and the strong host–guest complexation between C[5]OH and an electron-poor bipyridinium salt, paraquat G. The Ka value for the host–guest complex C[5]OH ⊃ G was calculated to be (1.09 ± 0.36) × 105 M−1 in ...
Bingbing Shi +6 more
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Potential molecular wires and molecular alligator clips
Nanotechnology, 1996The synthesis of oligo(2-ethylphenylene-ethynylene)s, oligo(2-(-ethylheptyl)phenylene-ethynylene)s, and oligo(3-ethylthiophene-ethynylene)s is described via an iterative divergent convergent approach. Synthesized were the monomer, dimer, tetramer, octamer and 16-mer of the oligo(3-ethylthiophene-ethynylene)s and oligo(2--ethylheptyl)phenylene ...
Jeffry S Schumm +4 more
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Semi-Rigid Molecular-Clip-Based Molecular Crystal Gearshift
ACS Applied Materials & Interfaces, 2018A new version of molecular clip, with a semi-rigid symmetrical crab-type architecture and flexible cavity size, has been successfully designed and synthesized via a one-pot Friedel-Crafts alkylation reaction. The X-ray single-crystal diffraction data provide a simple and intuitive explanation, not only for its well-preorganized and regulated ...
Jia-Rui Wu +3 more
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