Results 21 to 30 of about 18,532 (197)

Morpholine

open access: yes
The German Senate Commission for the Investigation of Health Hazards of Chemical Compounds in the Work Area (MAK Commission) has re-evaluated the occupational exposure limit value (maximum concentration at the workplace, MAK value) and the pregnancy risk group of morpholine [110-91-8] considering also irritating and sensitizing effects.
Hartwig, Andrea   +2 more
  +4 more sources

Metal-free one-pot synthesis of 2-substituted and 2,3-disubstituted morpholines from aziridines

open access: yesBeilstein Journal of Organic Chemistry, 2015
The metal-free synthesis of 2-substituted and 2,3-disubstituted morpholines through a one-pot strategy is described. A simple and inexpensive ammonium persulfate salt enables the reaction of aziridines with halogenated alcohols to proceed via an SN2-type
Hongnan Sun   +4 more
doaj   +1 more source

Ultrasonicated Synthesis of N-Benzyl-2,3-substituted Morpholines, via the Mitsunobu Diol Cyclisation

open access: yesE-Journal of Chemistry, 2010
A facile five step synthesis of N-benzyl-2,3-substituted morpholines (i-iii) was performed. The key steps were microwave assisted Friedel-crafts acylation and diol cyclization carried out via an ultra sonication of Mitsunobu reaction using DEAD ...
B. Jayachandra Reddy   +1 more
doaj   +1 more source

Determination of antimicrobial activity of some 1,2,4-triazole derivatives

open access: yesRegulatory Mechanisms in Biosystems, 2018
We carried out MIC of the derivatives of 1,2,4-triazole II (4-((5-nitrofuran-2-yl)methyleneamino)-1-propyl-4H-1,2,4-triazolium bromide) and I (N-((5-nitrofuran-2-yl)methylene)-4H-4-amino-1,2,4-triazolidium chloride) against Escherichia coli ATCC 3912/4 ...
M. S. M. Alrawashdeh
doaj   +1 more source

Photoactivated Platinum Complexes: Targeting Membrane Proteins and Organelles for Precision Cancer Therapy

open access: yesAngewandte Chemie, EarlyView.
This review highlights an emerging anticancer approach integrating platinum agents into photodynamic therapy (PDT) and photoactivated chemotherapy (PACT) systems, further augmented by cancer cell membrane‐ and organelle‐targeting. By directing photoactivated platinum complexes from nontargeted distribution to cancer cells or defined subcellular sites ...
Shu Chen   +3 more
wiley   +2 more sources

Electrochemical Intramolecular Oxytrifluoromethylation of N‑Tethered Alkenyl Alcohols: Synthesis of Functionalized Morpholines

open access: yes, 2020
An electrochemical intramolecular oxytrifluoromethylation of N-tethered alkenyl alcohols was developed providing straightforward access to CF3-containing morpholines derivatives.
Thibaut Courant (1525447)   +2 more
core   +1 more source

Chlorination‐Driven BODIPY Fluorescent Probes for the Selective Monitoring of Myeloperoxidase Activity in Cells and Inflamed Mouse Models

open access: yesAngewandte Chemie, EarlyView.
A meso‐carboxamide‐substituted BODIPY fluorescent probe reports myeloperoxidase (MPO) activity via electrophilic chlorination by MPO‐derived HOCl, generating a highly emissive chlorinated product with a ca. 40 nm bathochromic shift. Applications in quantitative MPO assays, cellular imaging of MPO‐derived HOCl, redox‐dependent discrimination of cancer ...
Siyoung Cho   +3 more
wiley   +2 more sources

One‐Component Carbon Dot Photoinitiator Enables High‐Fidelity Digital Light Processing 3D Printing With Improved Mechanical Resistance

open access: yesAdvanced Functional Materials, EarlyView.
Furfural carbon dots functionalized with acylphosphine oxide photosensitive groups (CD‐PO PI) demonstrate potential as one‐component photoinitiators for digital light processing (DLP) 3D printing. Compared to conventional diphenyl(2,4,6‐trimethylbenzoyl)phosphine oxide (TPO), CD‐PO PI offers improved printing resolution, resin toughness, and biological
Xiaotong Li   +10 more
wiley   +1 more source

Beetles “in red”: are the endangered flat bark beetles Cucujus cinnaberinus and C. haematodes chemically protected? (Coleoptera: Cucujidae)

open access: yesThe European Zoological Journal, 2018
Two native species of the genus Cucujus show a wide geographic distribution in Europe, Cucujus cinnaberinus (Scopoli, 1763) and C. haematodes Erichson, 1845.
T. Bonacci   +5 more
doaj   +1 more source

Nickel‐Catalyzed Three‐Component Difluoroalkylation‐Amination for the Direct Access to Anti‐Inflammatory β‐Difluoroalkyl Amines

open access: yesAdvanced Science, EarlyView.
A nickel‐catalyzed three‐component reductive fluoroalkylation‐amination strategy of N‐vinylamides for the direct access to the α‐amidyl‐β‐difluoroalkyl amines was reported here. The synthetic method features with broad substrate scope, mild conditions, high functional group tolerance, and convenience to handle.
Chang Xu   +8 more
wiley   +1 more source

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