Results 51 to 60 of about 18,857 (217)

Three-Step Synthesis of N-(7-chloro-4-morpholinoquinolin-2-yl)benzamide from 4,7-Dichloroquinoline

open access: yesMolbank
The quinoline derivative, N-(7-chloro-4-morpholinoquinolin-2-yl)benzamide, was synthesized in a conventional three-step procedure from 4,7-dichloroquinoline using a N-oxidation reaction/C2-amide formation reaction/C4 SNAr reaction sequence. The structure
Deiby F. Aparicio Acevedo   +2 more
doaj   +1 more source

Knockdown of zebrafish YY1a can downregulate the phosphatidylserine (PS) receptor expression, leading to induce the abnormal brain and heart development [PDF]

open access: yes, 2016
BACKGROUND: Yin Yang 1 (YY1) is a ubiquitously expressed GLI-Kruppel zinc finger-containing transcriptional regulator. YY1 plays a fundamental role in normal biologic processes such as embryogenesis, differentiation, and cellular proliferation.
Jen-Leih Wu   +4 more
core   +1 more source

Flipping the Card With Enantiodivergent Organocatalysis

open access: yesChemistry – A European Journal, EarlyView.
This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre   +3 more
wiley   +1 more source

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source

Estimating Half-Lives for Pesticide Dissipation from Plants [PDF]

open access: yes, 2014
Pesticide risk and impact assessment models critically rely on and are sensitive to information describing dissipation from plants. Despite recent progress, experimental data are not available for all relevant pesticide–plant combinations, and currently ...
Fantke, Peter   +3 more
core   +2 more sources

On the Planarity of Heterocyclic Bay‐Substituted Perylenediimides: Insight into the Fluorescent Photoinduced Electron Transfer Sensing Framework

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Near‐infrared fluorescent pH indicators based on perylenediimide were constructed in a modular receptor–spacer–fluorophore–spacer–receptor format with heterocyclic amino moieties at the bay positions. Counterintuitively, the dibrominated intermediate with two heavy atoms is more emissive than the heterocyclic compounds.
Luke Camenzuli   +4 more
wiley   +1 more source

Morpholines-(IV)

open access: yesZeitschrift für Naturforschung B, 1971
Cyclodehydrohalogenation-beta-Lactams-Morpholin-3-ones-H'-NMR Spectroscopy N-Aryl-N-chloroacetyl-2-chlorophenacylamines (2) give morpholinones 3, or beta-lactams 4, depending upon the N-aryl-substituent. N-Phenyl-N- (2,3-dibromo-3-phenylpropionyl) -4-nitrophenacylamine did not undergo base-catalysed cyclization but gave, instead, the α,β-
Riaz F. Abdulla, Alok N. Bannerji
openaire   +1 more source

Electrophilic Iodination of Heterocyclic Compounds. Recent Advances 2008–2025: Part II

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Electrophilic iodination using molecular iodine and iodide sources represents an efficient approach for accessing valuable iodinated organic compounds. This review highlights recent advances in the iodination of heterocyclic compounds from 2008 to 2025, emphasizing the role of heteroaryl iodides as important synthetic intermediates for biologically ...
Njomza Ajvazi, Stojan Stavber
wiley   +1 more source

Morpholines — (II)

open access: yesZeitschrift für Naturforschung B, 1970
The new route to the synthesis of 3-oxo-1,4-oxazines 1 has been extended. N-aryl-N-chloroacetyl-m-nitro-phenacyl amines afford either only oxazine, or beta-lactam or both depending on the nature of the N-aryl substituent. A set of rules indicates from which precursors beta-lactam, as against morpholine formation, may be expected.
Basanta G. Chatterjee   +2 more
openaire   +1 more source

Modular synthesis and transition metal-free alkynylation/alkenylation of Castagnoli–Cushmanderived N,O- and N,S-heterocyclic vinyl chlorides [PDF]

open access: yes, 2020
A modular and functional group-tolerant protocol for the transition metal-free coupling of novel N,O- and N,S-heterocyclic vinyl chlorides with terminal acetylenes and styrenes has been developed, leading to the epimerization-free synthesis of fully ...
Beng, Timothy K.   +2 more
core   +2 more sources

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