Catalysts generated from the trifluoroacetate‐bridged methylnaphthyl‐palladium dimer [Pd(1‐MeNAP)TFA]2 and biarylphosphine ligands in combination with the base LiHMDS promote α‐arylation reactions of various enolates with non‐activated aryl fluorides at room temperature.
Nele Krüger +4 more
wiley +1 more source
Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
N-Heterocyclic Carbenes: A Benchmark Study on their Singlet-Triplet Energy Gap as a Critical Molecular Descriptor. [PDF]
Zois KP, Danopoulos AA, Tzeli D.
europepmc +1 more source
A new class of cyclometalated metal complexes with pincer luminophores (C^N^O and N^C^O) is reported. They unite high photoluminescence efficiencies in liquid solutions at r.t. with tunable colors across the visible spectrum and convenient synthetic accessibility.
Joschua Lüke +4 more
wiley +1 more source
In-depth investigation into the binding capabilities of palladium-based N-heterocyclic carbenes towards five heavy metals: Hg, Cd, Pb, Cr, and As. [PDF]
Liu Q, Kong X, Li QR, Lan W.
europepmc +1 more source
Enantioselective lactonization catalyzed by chiral N-heterocyclic carbenes enables access to inherently chiral eight-membered lactones. [PDF]
Dočekal V +3 more
europepmc +1 more source
Cationic and Homoleptic Copper(I)-Thiazol-2-ylidenes: Highly Reactive Thiazole N-Heterocyclic Carbenes σ-Lewis Acid Catalysts. [PDF]
Wang R +7 more
europepmc +1 more source
Directed Synthesis of Gold Nanoparticle Superstructures Using Self-Assembling Peptoids Containing Metal-Bonding N-Heterocyclic Carbenes. [PDF]
Ge L +6 more
europepmc +1 more source
A Joyful Journey: Tungsten(VI) and Tungsten(V) Fluorides Meet N-Heterocyclic Carbenes and Cyclic (Alkyl)(Amino)Carbenes. [PDF]
Riethmann M +7 more
europepmc +1 more source

