β-Lactam Ylidenes: An Overlooked Class of N-Heterocyclic Carbenes. [PDF]
Karl L +3 more
europepmc +1 more source
Au(I) Complex With an Abnormal Carbene Ligand Shows Anti‐Kasha Dual Photoluminescence Emission
Incorporation of an abnormal N‐heterocyclic carbene into a heteroleptic linear Au(I) complex induces anti‐Kasha dual emission responsive to biologically relevant phenyl sulfate. ABSTRACT We report the first photoactive linear Au(I) complex with an abnormal N‐heterocyclic carbene (aNHC) ligand, Au(aIm)(Cz).
Natesan Mannangatti Rajendran +5 more
wiley +2 more sources
Reactions of N-heterocyclic carbenes with nitrobenzenes: harnessing NHCs as synthetic building blocks. [PDF]
Zheng Z +6 more
europepmc +1 more source
N-Heterocyclic Carbenes Carrying Weakly Coordinating Anions. [PDF]
Ho LP, Tamm M.
europepmc +1 more source
A general C─C cross‐coupling method employing earth‐abundant organoaluminium nucleophiles is enabled by electronically highly donating and sterically demanding ylide‐substituted phosphine (YPhos) ligands under Pd catalysis. This protocol represents an organoaluminium cross‐coupling that operates with a single catalyst system across all carbon ...
Nicolas Kaiser +3 more
wiley +1 more source
Kinetically Stable Boron‐Heteroatom Bonds
This study investigates the kinetic stability of boron‐heteroatom bonds in N‐methyliminodiacetic acid (MIDA) boronates. The hemilabile nature of the ligand enables the synthesis of molecules that would otherwise be considered too hydrolytically labile. Depending on the structure, acid‐promoted migration of the boryl group was found to produce compounds
Alina Trofimova +8 more
wiley +2 more sources
Cyclooctyne-Functionalized N-Heterocyclic Carbenes for Click Coupling of Sensing Oligonucleotides to Gold Surfaces. [PDF]
Nalaoh P +3 more
europepmc +1 more source
N-Heterocyclic Carbenes: Molecular Porters of Surface Mounted Ru-Porphyrins. [PDF]
Knecht P +14 more
europepmc +1 more source
Influence of the Size of the Metallacycle of P‐NHC Mn Complexes for the Hydrogenation of Esters
Does ring size matter? For manganese‐catalyzed ester hydrogenation, expanding the P‐NHC chelate ring from five to seven members unlocks superior activity at half the catalyst loading, shorter reaction times, and broader substrate scope, including the complete depolymerization of poly(ε‐caprolactone).
Romane Pointis +8 more
wiley +1 more source
Synthesis and Reactivity of Triphosphaallyl Cation Stabilized by N-Heterocyclic Carbenes. [PDF]
Frötschel-Rittmeyer J +8 more
europepmc +1 more source

