Results 161 to 170 of about 13,617,516 (263)

Au(I) Complex With an Abnormal Carbene Ligand Shows Anti‐Kasha Dual Photoluminescence Emission

open access: yesAngewandte Chemie, Volume 138, Issue 38, 14 September 2026.
Incorporation of an abnormal N‐heterocyclic carbene into a heteroleptic linear Au(I) complex induces anti‐Kasha dual emission responsive to biologically relevant phenyl sulfate. ABSTRACT We report the first photoactive linear Au(I) complex with an abnormal N‐heterocyclic carbene (aNHC) ligand, Au(aIm)(Cz).
Natesan Mannangatti Rajendran   +5 more
wiley   +2 more sources

Unlocking the Potential of Organoaluminum Reagents for Versatile C─C Couplings Using YPhos‐Pd Catalysts

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 18, 19 September 2026.
A general C─C cross‐coupling method employing earth‐abundant organoaluminium nucleophiles is enabled by electronically highly donating and sterically demanding ylide‐substituted phosphine (YPhos) ligands under Pd catalysis. This protocol represents an organoaluminium cross‐coupling that operates with a single catalyst system across all carbon ...
Nicolas Kaiser   +3 more
wiley   +1 more source

Kinetically Stable Boron‐Heteroatom Bonds

open access: yesAngewandte Chemie, Volume 138, Issue 38, 14 September 2026.
This study investigates the kinetic stability of boron‐heteroatom bonds in N‐methyliminodiacetic acid (MIDA) boronates. The hemilabile nature of the ligand enables the synthesis of molecules that would otherwise be considered too hydrolytically labile. Depending on the structure, acid‐promoted migration of the boryl group was found to produce compounds
Alina Trofimova   +8 more
wiley   +2 more sources

N-Heterocyclic Carbenes: Molecular Porters of Surface Mounted Ru-Porphyrins. [PDF]

open access: yesAngew Chem Int Ed Engl, 2022
Knecht P   +14 more
europepmc   +1 more source

Influence of the Size of the Metallacycle of P‐NHC Mn Complexes for the Hydrogenation of Esters

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 18, 19 September 2026.
Does ring size matter? For manganese‐catalyzed ester hydrogenation, expanding the P‐NHC chelate ring from five to seven members unlocks superior activity at half the catalyst loading, shorter reaction times, and broader substrate scope, including the complete depolymerization of poly(ε‐caprolactone).
Romane Pointis   +8 more
wiley   +1 more source

Synthesis and Reactivity of Triphosphaallyl Cation Stabilized by N-Heterocyclic Carbenes. [PDF]

open access: yesChemistry
Frötschel-Rittmeyer J   +8 more
europepmc   +1 more source

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