Results 141 to 150 of about 13,617,516 (263)

NMR "Finger Prints" of N-Heterocyclic Carbenes, DFT Analysis: Scopes and Limitations. [PDF]

Molecules, 2023
Kondrashova SA, Latypov SK.
europepmc   +1 more source

Super‐Electron‐Donor Polymers: From Monomer Design to Redox Functionality

Small, EarlyView.
2,2'‐Bipyridinylidenes are known for their “super‐electron‐donor” properties and have therefore been used beyond the field of organic synthesis. Their two‐electron redox process at a low potential of 1.8 V vs. Li/Li+ makes them attractive negative p‐type electrode‐active materials.
Luisa Rzesny, Aswadh Shyma Sajeevan, Caroline Schmidt, Johannes Lahr, Christoph Lorenz, Mathias Hermann, Nicolas Dupré, Stéven Renault, Philippe Poizot, Birgit Esser   +9 more
wiley   +1 more source

N-Heterocyclic carbenes on copper: a dynamic and sensitive interplay between surface functionalization and etching. [PDF]

Chem Sci
Nalop A, Sasmal HS, Schlosser L, Paweletz J, Tomut AC, Daniliuc CG, Jati A, Henz J, Lohrmann SM, Holtkamp M, Köhrer A, Schreiner F, Karst U, Ravoo BJ, Doltsinis N, Glorius F.   +15 more
europepmc   +1 more source

A Dynamic Surface Metal‐Organic Framework Electrocatalyst: Potential‐Driven Activation of Atomically Defined Au Sites for the Hydrogen Evolution Reaction

Small, EarlyView.
Operando EC‐STM reveals that an NHC‐based SMOF on Au(111), initially frozen in interconnected 1D chains, dynamically reconfigures under cathodic bias into a fluxional structure bearing undercoordinated Au sites while abstracting Au atoms from the support.
Paulina Wira, Leonardo Cielo, Zisheng Zhang, Mattia Cattelan, Rafał Lewandków, Dennis Pedersoli, Fujia Liu, Boyu Qie, Felix. R. Fischer, Francesco Sedona, Cristina Tubaro, Tomasz Kosmala, Stefano Agnoli   +12 more
wiley   +1 more source

Advances in Unconventional and Sustainable Synthetic Approaches to Benzopyran Scaffolds

The Chemical Record, EarlyView.
This review provides a comprehensive and critical analysis of low‐impact synthetic methodologies reported in the last 8 years (2018–2026) for the construction of benzopyran‐derived scaffolds, such as coumarins, flavones, chromones, chromenes, and chromanes. The benzopyran scaffold is a versatile family of heterocycles found in a wide range of bioactive
Nathalia B. Sá, Patrick C. Nobre, Isabelly O. Ferreira, Juliano B. Azeredo, Vanessa Nascimento   +4 more
wiley   +1 more source

IPr*^BndiNHC - sterically adaptable benzyl-linked dinuclear N-heterocyclic carbenes. [PDF]

Dalton Trans
Halikowska-Tarasek K, Dziuk B, Szostak R, Szostak M, Bisz E.   +4 more
europepmc   +1 more source

Oxaziridines: Versatile Reagents in Modern Organic Synthesis

The Chemical Record, EarlyView.
Being capable of transferring an O atom and N‐group/atom, oxaziridines are considered multitasking agents. These are employed for diverse organic transformations, such as epoxidation of olefins, α‐ and γ‐hydroxylation/amination of carbonyl compounds, oxidation of sulfides, [3+2]cycloaddition with unsaturated systems.
Ajeet Chandra, Subba Rao Cheekatla, Keshaba Nanda Parida   +2 more
wiley   +1 more source

Exclusive Hydroformylation of Terminal Olefins: A Phosphorus‐Free Ruthenium System for the Selective Functionalization of Complex Mixtures

Angewandte Chemie, Volume 138, Issue 39, 21 September 2026.
Development of a phosphorus‐free Ru/DBU catalyst enabling highly chemo‐ and regioselective hydroformylation of terminal olefins, sparing internal double bonds. Optimization of reaction parameters, ligand effects, and substrate scope including industrial feedstocks was realized.
Mohamed Niyaz Vellala Syed Ali, Ida Ziccarelli, Dilver Peña Fuentes, Christoph Kubis, Robert Franke, Ralf Jackstell, Matthias Beller   +6 more
wiley   +2 more sources

Author Correction: Single-gold etching at the hypercarbon atom of C-centred hexagold(I) clusters protected by chiral N-heterocyclic carbenes. [PDF]

Nat Commun
Pei XL, Zhao P, Ube H, Lei Z, Ehara M, Shionoya M.   +5 more
europepmc   +1 more source

Surface Ligand Engineering in Quantum Dot Photocatalysis: Mechanisms, Design Principles, and Applications

Advanced Chemical Engineering, Volume 1, Issue 2, December 2026.
Surface ligands govern quantum dot photocatalysis through thermodynamic band‐edge tuning, kinetic charge‐transfer regulation, and microenvironmental control. Rational ligand engineering, using short‐chain, inorganic, conjugated, or dual‐ligand systems, enables efficient solar fuel production, selective organic transformations, environmental remediation,
Yali Weng, Huakang Yang, Zining Zhang, Yue Zhou, Dongxiang Luo, Xiao Liu   +5 more
wiley   +1 more source