Results 121 to 130 of about 13,617,516 (263)
N-heterocyclic carbenes rhodium complexes: conformational analysis and catalytic studies
, 2010 Imidazolium salts incorporating functional groups represent a class of compounds having great versatility due to their wide range of applications as task specific ionic liquids (ILs)1 or N-heterocyclic carbene precursors (NHCs)2. Recently our research in
CASSANI, MARIA CRISTINA +5 more
core
Persilylated and Related Silyl Anion‐Induced Synthesis of Group 3–10 Metal–Silyl Complexes
Chemistry – A European Journal, EarlyView.Persilylated and related silyl anions serve as powerful tools for constructing metal–silyl complexes across group 3–10 elements. Their strong σ‐donating ability and steric bulk stabilize low‐coordinate, reactive species and enable unique bonding motifs.
Yusuke Sunada
wiley +1 more source
Chemistry – A European Journal, EarlyView.Balancing Act: Se─M bond serving as the fulcrum of the balance scale to compare the different weight of toxicity and therapeutic effects in biological environment. ABSTRACT The synthesis and characterization of organo‐selenium compounds have attracted considerable interest for decades, driven by the search for efficient catalysts and bioinspired ...
Matteo Filippi +6 more
wiley +1 more source
Recent advances in the chemistry and applications of N-heterocyclic carbenes
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still capture scientists’ interest as versatile, modular and strongly coordinating moieties.
Glorius F +3 more
core +4 more sources
Two‐Coordinate 13‐Electron PdI Complexes Stabilized by the Bulky DIMeIHeptCl NHC Ligand
Chemistry – A European Journal, EarlyView.Bulky N‐heterocyclic carbene (NHC) ligand DiMeIHeptCl stabilizes rare two‐coordinate 13‐electron PdI species. These monomeric complexes are directly observed crystallographically and by electron paramagnetic resonance (EPR) spectroscopy, and display unusual structures and radical‐type reactivity, forming Pd0(NHC) via Pd─X bond homolysis or ...
Volodymyr Semeniuchenko +8 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Naphthalene diimide–N‐heterocyclic carbene iridium complexes display uncommon multistimuli‐responsive behavior combining strong Cl(lp)···π interactions, ligand non‐innocence, visible‐light photoreduction, and conPET photocatalysis. The study also provides new insight into the interaction of NDI platforms with fluoride/basic anions, revealing unexpected
Maite Silva‐Muñoz +2 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Easily synthesized [Ge([12]crown‐4)2][OTf]2 catalyzes the hydrosilylation of aldehydes to give reductively coupled ethers via a carbonyl‐activated reaction pathway. The mechanism proceeds through two distinct steps: hydrosilylation followed by etherification. The open coordination face of the active cationic Ge(II) catalyst facilitates the coordination
Sarah L. McOnie +2 more
wiley +1 more source
Trends and Future Directions in Organic Chemistry for Drug Discovery
Chemistry – A European Journal, EarlyView.Organic synthesis is being reshaped by the convergence of catalytic innovation, automation, artificial intelligence, and emerging therapeutic modalities. Late‐stage functionalization, photoredox and electrochemical methods, biocatalysis, flow chemistry, DELs, and proximity‐based drugs are examined as components of closed‐loop discovery.
Paweł Kozyra, Maciej Masłyk
wiley +1 more source
ChemistryEuropeThe reactivity analysis of dipotassiumgermoldiides K2[1] with aluminum trichloride in the presence of donors uncovers an unexpectedly broad range of products.
Lena Albers +2 more
doaj +1 more source