Wingtip-Flexible N-Heterocyclic Carbenes: Unsymmetrical Connection between IMes and IPr. [PDF]
Zhao Q +6 more
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Eliminating creep in vitrimers using temperature-resilient siloxane exchange chemistry and N-heterocyclic carbenes. [PDF]
Debsharma T +7 more
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Photoinduced Single Electron Reduction of the 4-O-5 Linkage in Lignin Models for C-P Coupling Catalyzed by Bifunctional N-Heterocyclic Carbenes. [PDF]
Liu Q +6 more
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IPr<sup>#</sup> Complexes-Highly-Hindered, Sterically-Bulky Cu(I) and Ag(I) N-Heterocyclic Carbenes: Synthesis, Characterization, and Reactivity. [PDF]
Utecht-Jarzyńska G +6 more
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C(sp<sup>2</sup>)-C(sp<sup>2</sup>) and C(sp<sup>2</sup>)-C(sp<sup>3</sup>) Nickel-Catalyzed Kumada-Corriu and Buchwald-Hartwig Cross-Coupling of Aryl Sulfamates Enabled by Sterically-Demanding, Electron-Rich IPr*<sup>OMe</sup> N-Heterocyclic Carbenes. [PDF]
Kardela M, Szostak M, Bisz E.
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Ambiphilicity of ring-expanded N-heterocyclic carbenes. [PDF]
Vermersch F +4 more
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NMR Spectroscopic Signatures of Cationic Surface Sites from Supported Coinage Metals Interacting with N-Heterocyclic Carbenes. [PDF]
Dery S, Cao W, Yao C, Copéret C.
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N‐Heterocyclic Carbenes as Organocatalysts
Angewandte Chemie International Edition, 2007AbstractOrganocatalyzed reactions represent an attractive alternative to metal‐catalyzed processes notably because of their lower cost and benign environmental impact in comparison to organometallic catalysis. In this context, N‐heterocyclic carbenes (NHCs) have been studied for their ability to promote primarily the benzoin condensation.
Nicolas, Marion +2 more
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An overview of N-heterocyclic carbenes
Nature, 2014The successful isolation and characterization of an N-heterocyclic carbene in 1991 opened up a new class of organic compounds for investigation. From these beginnings as academic curiosities, N-heterocyclic carbenes today rank among the most powerful tools in organic chemistry, with numerous applications in commercially important processes.
Matthew N, Hopkinson +3 more
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N-Heterocyclic carbenes in gold catalysis
Chemical Society Reviews, 2008The appealing properties of N-heterocyclic carbenes (NHC) as ancillary ligands and the high potential of gold as an organometallic catalyst have made their encounter inevitable. Still in its infancy, NHC-gold catalysis is nevertheless growing rapidly.
Nicolas, Marion, Steven P, Nolan
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